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Undecacarbonyl-1κ(3) C,2κ(4) C,3κ(4) C-[tris(2-chloroethyl) phosphite-1κP]-triangulo-triruthenium(0)
In the title triangulo-triruthenium compound, [Ru(3)(C(6)H(12)Cl(3)O(3)P)(CO)(11)], one equatorial carbonyl ligand is substituted by a monodentate phosphite ligand, leaving one equatorial and two axial carbonyl ligands on one Ru atom. The remaining two Ru atoms each carry two equatorial and two axia...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983316/ https://www.ncbi.nlm.nih.gov/pubmed/21587355 http://dx.doi.org/10.1107/S1600536810033891 |
| _version_ | 1782191852542230528 |
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| author | Shawkataly, Omar bin Ghani, Syed Sauban Jothiramalingam, Rajabathar Yeap, Chin Sing Fun, Hoong-Kun |
| author_facet | Shawkataly, Omar bin Ghani, Syed Sauban Jothiramalingam, Rajabathar Yeap, Chin Sing Fun, Hoong-Kun |
| author_sort | Shawkataly, Omar bin |
| collection | PubMed |
| description | In the title triangulo-triruthenium compound, [Ru(3)(C(6)H(12)Cl(3)O(3)P)(CO)(11)], one equatorial carbonyl ligand is substituted by a monodentate phosphite ligand, leaving one equatorial and two axial carbonyl ligands on one Ru atom. The remaining two Ru atoms each carry two equatorial and two axial terminal carbonyl ligands. In the crystal structure, the molecules are linked into a one-dimensional column along [100] by intermolecular C—H⋯O hydrogen bonds. |
| format | Text |
| id | pubmed-2983316 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29833162010-12-30 Undecacarbonyl-1κ(3) C,2κ(4) C,3κ(4) C-[tris(2-chloroethyl) phosphite-1κP]-triangulo-triruthenium(0) Shawkataly, Omar bin Ghani, Syed Sauban Jothiramalingam, Rajabathar Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title triangulo-triruthenium compound, [Ru(3)(C(6)H(12)Cl(3)O(3)P)(CO)(11)], one equatorial carbonyl ligand is substituted by a monodentate phosphite ligand, leaving one equatorial and two axial carbonyl ligands on one Ru atom. The remaining two Ru atoms each carry two equatorial and two axial terminal carbonyl ligands. In the crystal structure, the molecules are linked into a one-dimensional column along [100] by intermolecular C—H⋯O hydrogen bonds. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983316/ /pubmed/21587355 http://dx.doi.org/10.1107/S1600536810033891 Text en © Shawkataly et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shawkataly, Omar bin Ghani, Syed Sauban Jothiramalingam, Rajabathar Yeap, Chin Sing Fun, Hoong-Kun Undecacarbonyl-1κ(3) C,2κ(4) C,3κ(4) C-[tris(2-chloroethyl) phosphite-1κP]-triangulo-triruthenium(0) |
| title | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-[tris(2-chloroethyl) phosphite-1κP]-triangulo-triruthenium(0) |
| title_full | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-[tris(2-chloroethyl) phosphite-1κP]-triangulo-triruthenium(0) |
| title_fullStr | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-[tris(2-chloroethyl) phosphite-1κP]-triangulo-triruthenium(0) |
| title_full_unstemmed | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-[tris(2-chloroethyl) phosphite-1κP]-triangulo-triruthenium(0) |
| title_short | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-[tris(2-chloroethyl) phosphite-1κP]-triangulo-triruthenium(0) |
| title_sort | undecacarbonyl-1κ(3)
c,2κ(4)
c,3κ(4)
c-[tris(2-chloroethyl) phosphite-1κp]-triangulo-triruthenium(0) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983316/ https://www.ncbi.nlm.nih.gov/pubmed/21587355 http://dx.doi.org/10.1107/S1600536810033891 |
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