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Methyl 2-methoxy-4-{[2-(4-nitrophenyl)hydrazinylidene]methyl}benzoate
The molecule of the title Schiff base compound, C(16)H(15)N(3)O(5), obtained from a condensation reaction of 4-acetoxy-3-methoxybenzaldehyde and 4-nitrophenylhydrazine, adopts an E geometry with respect to the C=N double bond. The molecule is roughly planar, with the two benzene rings twisted...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983317/ https://www.ncbi.nlm.nih.gov/pubmed/21587632 http://dx.doi.org/10.1107/S160053681003802X |
Sumario: | The molecule of the title Schiff base compound, C(16)H(15)N(3)O(5), obtained from a condensation reaction of 4-acetoxy-3-methoxybenzaldehyde and 4-nitrophenylhydrazine, adopts an E geometry with respect to the C=N double bond. The molecule is roughly planar, with the two benzene rings twisted slightly with respect to each other by a dihedral angle of 6.90 (9)°. In the crystal, intermolecular N—H⋯O hydrogen bonds link centrosymmetrically related pairs of molecules, forming dimers of R (2) (2)(22) graph-set motif. The dimers are further connected through slipped π–π interactions between symmetry-related benzene rings [centroid–centroid distance of 3.646 (1) Å, offset angle of 15.4°]. |
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