Bis(2-amino­pyrimidine-κN (1))aqua­(nitrato-κO)(nitrato-κ(2) O,O′)zinc(II)

The water-coordinated Zn atom in the title monoaqua zinc nitrate adduct of 2-amino­pyrimidine, [Zn(NO(3))(2)(C(4)H(5)N(3))(2)(H(2)O)], is bonded to a monodentate nitrate ion and is chelated by the other nitrate ion. The heterocyclic ligands coordinate through ring N-donor sites. The coordination geo...

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Detalles Bibliográficos
Autores principales: Gao, Shan, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983322/
https://www.ncbi.nlm.nih.gov/pubmed/21587423
http://dx.doi.org/10.1107/S1600536810036731
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author Gao, Shan
Ng, Seik Weng
author_facet Gao, Shan
Ng, Seik Weng
author_sort Gao, Shan
collection PubMed
description The water-coordinated Zn atom in the title monoaqua zinc nitrate adduct of 2-amino­pyrimidine, [Zn(NO(3))(2)(C(4)H(5)N(3))(2)(H(2)O)], is bonded to a monodentate nitrate ion and is chelated by the other nitrate ion. The heterocyclic ligands coordinate through ring N-donor sites. The coordination geometry about the Zn(II) atom is a distorted octa­hedron. Intra­molecular N—H⋯O hydrogen bonds occur. In the crystal, adjacent adduct mol­ecules are linked by O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds into a layer motif parallel to (001).
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spelling pubmed-29833222010-12-30 Bis(2-amino­pyrimidine-κN (1))aqua­(nitrato-κO)(nitrato-κ(2) O,O′)zinc(II) Gao, Shan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The water-coordinated Zn atom in the title monoaqua zinc nitrate adduct of 2-amino­pyrimidine, [Zn(NO(3))(2)(C(4)H(5)N(3))(2)(H(2)O)], is bonded to a monodentate nitrate ion and is chelated by the other nitrate ion. The heterocyclic ligands coordinate through ring N-donor sites. The coordination geometry about the Zn(II) atom is a distorted octa­hedron. Intra­molecular N—H⋯O hydrogen bonds occur. In the crystal, adjacent adduct mol­ecules are linked by O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds into a layer motif parallel to (001). International Union of Crystallography 2010-09-18 /pmc/articles/PMC2983322/ /pubmed/21587423 http://dx.doi.org/10.1107/S1600536810036731 Text en © Gao and Ng 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Shan
Ng, Seik Weng
Bis(2-amino­pyrimidine-κN (1))aqua­(nitrato-κO)(nitrato-κ(2) O,O′)zinc(II)
title Bis(2-amino­pyrimidine-κN (1))aqua­(nitrato-κO)(nitrato-κ(2) O,O′)zinc(II)
title_full Bis(2-amino­pyrimidine-κN (1))aqua­(nitrato-κO)(nitrato-κ(2) O,O′)zinc(II)
title_fullStr Bis(2-amino­pyrimidine-κN (1))aqua­(nitrato-κO)(nitrato-κ(2) O,O′)zinc(II)
title_full_unstemmed Bis(2-amino­pyrimidine-κN (1))aqua­(nitrato-κO)(nitrato-κ(2) O,O′)zinc(II)
title_short Bis(2-amino­pyrimidine-κN (1))aqua­(nitrato-κO)(nitrato-κ(2) O,O′)zinc(II)
title_sort bis(2-amino­pyrimidine-κn (1))aqua­(nitrato-κo)(nitrato-κ(2) o,o′)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983322/
https://www.ncbi.nlm.nih.gov/pubmed/21587423
http://dx.doi.org/10.1107/S1600536810036731
work_keys_str_mv AT gaoshan bis2aminopyrimidinekn1aquanitratokonitratok2oozincii
AT ngseikweng bis2aminopyrimidinekn1aquanitratokonitratok2oozincii

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