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Acetato­(N-[(E)-1-(6-methyl-2-pyrid­yl)methyl­idene]-2-{2-[(E)-1-(6-methyl-2-pyrid­yl)methyl­idene­amino]­pheneth­yl}aniline)nickel(II) perchlorate

In the title complex, [Ni(CH(3)COO)(C(28)H(26)N(4))]ClO(4), the Ni(II) atom is coordinated by two imine N atoms and two pyridine N atoms of the N-[(E)-1-(6-methyl-2-pyrid­yl)methyl­idene]-2-(2-[(E)-1-(6-methyl-2-pyrid­yl)methyl­idene­amino]­pheneth­yl)aniline donor ligand and two O atoms of the acet...

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Detalles Bibliográficos
Autores principales: Sarkar, Shuranjan, Lee, Hajin, Lee, Hong-In
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983324/
https://www.ncbi.nlm.nih.gov/pubmed/21587350
http://dx.doi.org/10.1107/S1600536810034446
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author Sarkar, Shuranjan
Lee, Hajin
Lee, Hong-In
author_facet Sarkar, Shuranjan
Lee, Hajin
Lee, Hong-In
author_sort Sarkar, Shuranjan
collection PubMed
description In the title complex, [Ni(CH(3)COO)(C(28)H(26)N(4))]ClO(4), the Ni(II) atom is coordinated by two imine N atoms and two pyridine N atoms of the N-[(E)-1-(6-methyl-2-pyrid­yl)methyl­idene]-2-(2-[(E)-1-(6-methyl-2-pyrid­yl)methyl­idene­amino]­pheneth­yl)aniline donor ligand and two O atoms of the acetate ion in a distorted octa­hedral coordination. The average Ni—N and Ni—O bond lengths are 2.131 (13) and 2.098 (11) Å, respectively. An intramolecular N—H⋯O inter­action occurs. Relatively weak inter­molecular C—H⋯O inter­actions between the ligands and the ClO(4) (−) ions result in a chain extending along the b axis.
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spelling pubmed-29833242010-12-30 Acetato­(N-[(E)-1-(6-methyl-2-pyrid­yl)methyl­idene]-2-{2-[(E)-1-(6-methyl-2-pyrid­yl)methyl­idene­amino]­pheneth­yl}aniline)nickel(II) perchlorate Sarkar, Shuranjan Lee, Hajin Lee, Hong-In Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(CH(3)COO)(C(28)H(26)N(4))]ClO(4), the Ni(II) atom is coordinated by two imine N atoms and two pyridine N atoms of the N-[(E)-1-(6-methyl-2-pyrid­yl)methyl­idene]-2-(2-[(E)-1-(6-methyl-2-pyrid­yl)methyl­idene­amino]­pheneth­yl)aniline donor ligand and two O atoms of the acetate ion in a distorted octa­hedral coordination. The average Ni—N and Ni—O bond lengths are 2.131 (13) and 2.098 (11) Å, respectively. An intramolecular N—H⋯O inter­action occurs. Relatively weak inter­molecular C—H⋯O inter­actions between the ligands and the ClO(4) (−) ions result in a chain extending along the b axis. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983324/ /pubmed/21587350 http://dx.doi.org/10.1107/S1600536810034446 Text en © Sarkar et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sarkar, Shuranjan
Lee, Hajin
Lee, Hong-In
Acetato­(N-[(E)-1-(6-methyl-2-pyrid­yl)methyl­idene]-2-{2-[(E)-1-(6-methyl-2-pyrid­yl)methyl­idene­amino]­pheneth­yl}aniline)nickel(II) perchlorate
title Acetato­(N-[(E)-1-(6-methyl-2-pyrid­yl)methyl­idene]-2-{2-[(E)-1-(6-methyl-2-pyrid­yl)methyl­idene­amino]­pheneth­yl}aniline)nickel(II) perchlorate
title_full Acetato­(N-[(E)-1-(6-methyl-2-pyrid­yl)methyl­idene]-2-{2-[(E)-1-(6-methyl-2-pyrid­yl)methyl­idene­amino]­pheneth­yl}aniline)nickel(II) perchlorate
title_fullStr Acetato­(N-[(E)-1-(6-methyl-2-pyrid­yl)methyl­idene]-2-{2-[(E)-1-(6-methyl-2-pyrid­yl)methyl­idene­amino]­pheneth­yl}aniline)nickel(II) perchlorate
title_full_unstemmed Acetato­(N-[(E)-1-(6-methyl-2-pyrid­yl)methyl­idene]-2-{2-[(E)-1-(6-methyl-2-pyrid­yl)methyl­idene­amino]­pheneth­yl}aniline)nickel(II) perchlorate
title_short Acetato­(N-[(E)-1-(6-methyl-2-pyrid­yl)methyl­idene]-2-{2-[(E)-1-(6-methyl-2-pyrid­yl)methyl­idene­amino]­pheneth­yl}aniline)nickel(II) perchlorate
title_sort acetato­(n-[(e)-1-(6-methyl-2-pyrid­yl)methyl­idene]-2-{2-[(e)-1-(6-methyl-2-pyrid­yl)methyl­idene­amino]­pheneth­yl}aniline)nickel(ii) perchlorate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983324/
https://www.ncbi.nlm.nih.gov/pubmed/21587350
http://dx.doi.org/10.1107/S1600536810034446
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