6,7-Dihydro-5H-1,4-diazepino[1,2,3,4-lmn][1,10]phenanthroline-4,8-diium tris­(thio­cyanato-κN)cuprate(I)

The title copper(I) salt, (C(15)H(14)N(2))[Cu(NCS)(3)], exists as non-inter­acting cations and trigonal–planar anions. The cation is buckled, the r.m.s. deviation of the atoms passing through the phenanthroline portion being 0.16 Å. The Cu(I) atom is displaced by 0.019 (2) Å out of the N(3) triangle...

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Detalles Bibliográficos
Autores principales: Xu, Na, Niu, Yun-Yin, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983325/
https://www.ncbi.nlm.nih.gov/pubmed/21587424
http://dx.doi.org/10.1107/S1600536810036779
Descripción
Sumario:The title copper(I) salt, (C(15)H(14)N(2))[Cu(NCS)(3)], exists as non-inter­acting cations and trigonal–planar anions. The cation is buckled, the r.m.s. deviation of the atoms passing through the phenanthroline portion being 0.16 Å. The Cu(I) atom is displaced by 0.019 (2) Å out of the N(3) triangle. The crystal studied was a non-merohedral twin with twin domains in an approximate ratio of 55:45.

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