6,7-Dihydro-5H-1,4-diazepino[1,2,3,4-lmn][1,10]phenanthroline-4,8-diium tris­(thio­cyanato-κN)cuprate(I)

The title copper(I) salt, (C(15)H(14)N(2))[Cu(NCS)(3)], exists as non-inter­acting cations and trigonal–planar anions. The cation is buckled, the r.m.s. deviation of the atoms passing through the phenanthroline portion being 0.16 Å. The Cu(I) atom is displaced by 0.019 (2) Å out of the N(3) triangle...

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Detalles Bibliográficos
Autores principales: Xu, Na, Niu, Yun-Yin, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983325/
https://www.ncbi.nlm.nih.gov/pubmed/21587424
http://dx.doi.org/10.1107/S1600536810036779
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author Xu, Na
Niu, Yun-Yin
Ng, Seik Weng
author_facet Xu, Na
Niu, Yun-Yin
Ng, Seik Weng
author_sort Xu, Na
collection PubMed
description The title copper(I) salt, (C(15)H(14)N(2))[Cu(NCS)(3)], exists as non-inter­acting cations and trigonal–planar anions. The cation is buckled, the r.m.s. deviation of the atoms passing through the phenanthroline portion being 0.16 Å. The Cu(I) atom is displaced by 0.019 (2) Å out of the N(3) triangle. The crystal studied was a non-merohedral twin with twin domains in an approximate ratio of 55:45.
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spelling pubmed-29833252010-12-30 6,7-Dihydro-5H-1,4-diazepino[1,2,3,4-lmn][1,10]phenanthroline-4,8-diium tris­(thio­cyanato-κN)cuprate(I) Xu, Na Niu, Yun-Yin Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title copper(I) salt, (C(15)H(14)N(2))[Cu(NCS)(3)], exists as non-inter­acting cations and trigonal–planar anions. The cation is buckled, the r.m.s. deviation of the atoms passing through the phenanthroline portion being 0.16 Å. The Cu(I) atom is displaced by 0.019 (2) Å out of the N(3) triangle. The crystal studied was a non-merohedral twin with twin domains in an approximate ratio of 55:45. International Union of Crystallography 2010-09-18 /pmc/articles/PMC2983325/ /pubmed/21587424 http://dx.doi.org/10.1107/S1600536810036779 Text en © Xu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Na
Niu, Yun-Yin
Ng, Seik Weng
6,7-Dihydro-5H-1,4-diazepino[1,2,3,4-lmn][1,10]phenanthroline-4,8-diium tris­(thio­cyanato-κN)cuprate(I)
title 6,7-Dihydro-5H-1,4-diazepino[1,2,3,4-lmn][1,10]phenanthroline-4,8-diium tris­(thio­cyanato-κN)cuprate(I)
title_full 6,7-Dihydro-5H-1,4-diazepino[1,2,3,4-lmn][1,10]phenanthroline-4,8-diium tris­(thio­cyanato-κN)cuprate(I)
title_fullStr 6,7-Dihydro-5H-1,4-diazepino[1,2,3,4-lmn][1,10]phenanthroline-4,8-diium tris­(thio­cyanato-κN)cuprate(I)
title_full_unstemmed 6,7-Dihydro-5H-1,4-diazepino[1,2,3,4-lmn][1,10]phenanthroline-4,8-diium tris­(thio­cyanato-κN)cuprate(I)
title_short 6,7-Dihydro-5H-1,4-diazepino[1,2,3,4-lmn][1,10]phenanthroline-4,8-diium tris­(thio­cyanato-κN)cuprate(I)
title_sort 6,7-dihydro-5h-1,4-diazepino[1,2,3,4-lmn][1,10]phenanthroline-4,8-diium tris­(thio­cyanato-κn)cuprate(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983325/
https://www.ncbi.nlm.nih.gov/pubmed/21587424
http://dx.doi.org/10.1107/S1600536810036779
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AT ngseikweng 67dihydro5h14diazepino1234lmn110phenanthroline48diiumtristhiocyanatokncupratei

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