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6,7-Dihydro-5H-1,4-diazepino[1,2,3,4-lmn][1,10]phenanthroline-4,8-diium tris­(thio­cyanato-κN)cuprate(I)

The title copper(I) salt, (C(15)H(14)N(2))[Cu(NCS)(3)], exists as non-inter­acting cations and trigonal–planar anions. The cation is buckled, the r.m.s. deviation of the atoms passing through the phenanthroline portion being 0.16 Å. The Cu(I) atom is displaced by 0.019 (2) Å out of the N(3) triangle...

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Detalles Bibliográficos
Autores principales: Xu, Na, Niu, Yun-Yin, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983325/
https://www.ncbi.nlm.nih.gov/pubmed/21587424
http://dx.doi.org/10.1107/S1600536810036779