Bis(di-2-pyridyl­methane­diol-κ(3) N,O,N′)nickel(II) dibenzoate

The title compound, [Ni(C(11)H(10)N(2)O(2))(2)](C(7)H(5)O(2))(2), consists of an Ni(II) ion coordinated by two tridentate chelating (2-py)(2)C(OH)(2) ligands (py is pyrid­yl) and two benzoate anions. The Ni(II) ion is located on a twofold rotation axis, and its geometry is distorted octa­hedral. The...

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Detalles Bibliográficos
Autores principales: Kim, Jin Hoon, Kim, Du-Hyun, Kim, Pan-Gi, Kim, Cheal, Kim, Youngmee
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983329/
https://www.ncbi.nlm.nih.gov/pubmed/21587425
http://dx.doi.org/10.1107/S160053681003669X
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author Kim, Jin Hoon
Kim, Du-Hyun
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
author_facet Kim, Jin Hoon
Kim, Du-Hyun
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
author_sort Kim, Jin Hoon
collection PubMed
description The title compound, [Ni(C(11)H(10)N(2)O(2))(2)](C(7)H(5)O(2))(2), consists of an Ni(II) ion coordinated by two tridentate chelating (2-py)(2)C(OH)(2) ligands (py is pyrid­yl) and two benzoate anions. The Ni(II) ion is located on a twofold rotation axis, and its geometry is distorted octa­hedral. The gem-diol ligand (2-py)(2)C(OH)(2) adopts an η(1):η(1):η(1) coordination mode. There are O—H⋯O hydrogen bonds between the gem-diol ligands and benzoate anions.
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spelling pubmed-29833292010-12-30 Bis(di-2-pyridyl­methane­diol-κ(3) N,O,N′)nickel(II) dibenzoate Kim, Jin Hoon Kim, Du-Hyun Kim, Pan-Gi Kim, Cheal Kim, Youngmee Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(11)H(10)N(2)O(2))(2)](C(7)H(5)O(2))(2), consists of an Ni(II) ion coordinated by two tridentate chelating (2-py)(2)C(OH)(2) ligands (py is pyrid­yl) and two benzoate anions. The Ni(II) ion is located on a twofold rotation axis, and its geometry is distorted octa­hedral. The gem-diol ligand (2-py)(2)C(OH)(2) adopts an η(1):η(1):η(1) coordination mode. There are O—H⋯O hydrogen bonds between the gem-diol ligands and benzoate anions. International Union of Crystallography 2010-09-18 /pmc/articles/PMC2983329/ /pubmed/21587425 http://dx.doi.org/10.1107/S160053681003669X Text en © Kim et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kim, Jin Hoon
Kim, Du-Hyun
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
Bis(di-2-pyridyl­methane­diol-κ(3) N,O,N′)nickel(II) dibenzoate
title Bis(di-2-pyridyl­methane­diol-κ(3) N,O,N′)nickel(II) dibenzoate
title_full Bis(di-2-pyridyl­methane­diol-κ(3) N,O,N′)nickel(II) dibenzoate
title_fullStr Bis(di-2-pyridyl­methane­diol-κ(3) N,O,N′)nickel(II) dibenzoate
title_full_unstemmed Bis(di-2-pyridyl­methane­diol-κ(3) N,O,N′)nickel(II) dibenzoate
title_short Bis(di-2-pyridyl­methane­diol-κ(3) N,O,N′)nickel(II) dibenzoate
title_sort bis(di-2-pyridyl­methane­diol-κ(3) n,o,n′)nickel(ii) dibenzoate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983329/
https://www.ncbi.nlm.nih.gov/pubmed/21587425
http://dx.doi.org/10.1107/S160053681003669X
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