[(Methyl­carbamothio­yl)disulfan­yl]methyl N-methyl­carbamodithio­ate

The title compound, C(5)H(10)N(2)S(5), was unintentionally obtained as the product of an attempted synthesis of a methyl­carbamodithioic acid using methyl­amine and carbon disulfide. In the mol­ecule, two dithio­carbamate groups are bridged by a –CH(2)S– unit. The C—S—S—C torsion angle is −90.13 (11...

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Autores principales: Khan, Hizbullah, Aziz, Muhammad, Neuhausen, Christine, Murtaza, Ghulam, Shaheen, Farkhanda
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983331/
https://www.ncbi.nlm.nih.gov/pubmed/21587641
http://dx.doi.org/10.1107/S160053681003833X
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author Khan, Hizbullah
Aziz, Muhammad
Neuhausen, Christine
Murtaza, Ghulam
Shaheen, Farkhanda
author_facet Khan, Hizbullah
Aziz, Muhammad
Neuhausen, Christine
Murtaza, Ghulam
Shaheen, Farkhanda
author_sort Khan, Hizbullah
collection PubMed
description The title compound, C(5)H(10)N(2)S(5), was unintentionally obtained as the product of an attempted synthesis of a methyl­carbamodithioic acid using methyl­amine and carbon disulfide. In the mol­ecule, two dithio­carbamate groups are bridged by a –CH(2)S– unit. The C—S—S—C torsion angle is −90.13 (11)°. The crystal structure is stabilized by N—H⋯S inter­actions between neighbouring mol­ecules. An intra­molecular N—H⋯S hydrogen bond also occurs.
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spelling pubmed-29833312010-12-30 [(Methyl­carbamothio­yl)disulfan­yl]methyl N-methyl­carbamodithio­ate Khan, Hizbullah Aziz, Muhammad Neuhausen, Christine Murtaza, Ghulam Shaheen, Farkhanda Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(5)H(10)N(2)S(5), was unintentionally obtained as the product of an attempted synthesis of a methyl­carbamodithioic acid using methyl­amine and carbon disulfide. In the mol­ecule, two dithio­carbamate groups are bridged by a –CH(2)S– unit. The C—S—S—C torsion angle is −90.13 (11)°. The crystal structure is stabilized by N—H⋯S inter­actions between neighbouring mol­ecules. An intra­molecular N—H⋯S hydrogen bond also occurs. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983331/ /pubmed/21587641 http://dx.doi.org/10.1107/S160053681003833X Text en © Khan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Khan, Hizbullah
Aziz, Muhammad
Neuhausen, Christine
Murtaza, Ghulam
Shaheen, Farkhanda
[(Methyl­carbamothio­yl)disulfan­yl]methyl N-methyl­carbamodithio­ate
title [(Methyl­carbamothio­yl)disulfan­yl]methyl N-methyl­carbamodithio­ate
title_full [(Methyl­carbamothio­yl)disulfan­yl]methyl N-methyl­carbamodithio­ate
title_fullStr [(Methyl­carbamothio­yl)disulfan­yl]methyl N-methyl­carbamodithio­ate
title_full_unstemmed [(Methyl­carbamothio­yl)disulfan­yl]methyl N-methyl­carbamodithio­ate
title_short [(Methyl­carbamothio­yl)disulfan­yl]methyl N-methyl­carbamodithio­ate
title_sort [(methyl­carbamothio­yl)disulfan­yl]methyl n-methyl­carbamodithio­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983331/
https://www.ncbi.nlm.nih.gov/pubmed/21587641
http://dx.doi.org/10.1107/S160053681003833X
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AT murtazaghulam methylcarbamothioyldisulfanylmethylnmethylcarbamodithioate
AT shaheenfarkhanda methylcarbamothioyldisulfanylmethylnmethylcarbamodithioate

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