(Dimethyl­formamide)(2-methyl­propen­oato)[tris­(1-methyl-1H-benzimidazol-2-ylmeth­yl)amine]­manganese(II) perchlorate dimethyl­formamide solvate

In the title complex, [Mn(C(4)H(5)O(2))(C(27)H(27)N(7))(C(3)H(7)NO)]ClO(4)·C(3)H(7)NO, the Mn(II) ion is seven-coordinated in a distorted monocapped trigonal-prismatic geometry formed by a tetra­dentate tris­(1-methyl-1H-benzimidazol-2-ylmeth­yl)amine mol­ecule, a bidentate 2-methacrylate anion and...

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Detalles Bibliográficos
Autores principales: Wu, Huilu, Jia, Fei, Kong, Jin, Kou, Fan, Yuan, Jingkun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983334/
https://www.ncbi.nlm.nih.gov/pubmed/21587415
http://dx.doi.org/10.1107/S1600536810036457
Descripción
Sumario:In the title complex, [Mn(C(4)H(5)O(2))(C(27)H(27)N(7))(C(3)H(7)NO)]ClO(4)·C(3)H(7)NO, the Mn(II) ion is seven-coordinated in a distorted monocapped trigonal-prismatic geometry formed by a tetra­dentate tris­(1-methyl-1H-benzimidazol-2-ylmeth­yl)amine mol­ecule, a bidentate 2-methacrylate anion and a dimethyl­formamide mol­ecule. The methyl groups of the coordinated dimethyl­formamide mol­ecule and the perchlorate anions are disordered over two positions with occupancy factors of 0.640 (8) and 0.360 (8).

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