(Dimethyl­formamide)(2-methyl­propen­oato)[tris­(1-methyl-1H-benzimidazol-2-ylmeth­yl)amine]­manganese(II) perchlorate dimethyl­formamide solvate

In the title complex, [Mn(C(4)H(5)O(2))(C(27)H(27)N(7))(C(3)H(7)NO)]ClO(4)·C(3)H(7)NO, the Mn(II) ion is seven-coordinated in a distorted monocapped trigonal-prismatic geometry formed by a tetra­dentate tris­(1-methyl-1H-benzimidazol-2-ylmeth­yl)amine mol­ecule, a bidentate 2-methacrylate anion and...

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Detalles Bibliográficos
Autores principales: Wu, Huilu, Jia, Fei, Kong, Jin, Kou, Fan, Yuan, Jingkun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983334/
https://www.ncbi.nlm.nih.gov/pubmed/21587415
http://dx.doi.org/10.1107/S1600536810036457
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author Wu, Huilu
Jia, Fei
Kong, Jin
Kou, Fan
Yuan, Jingkun
author_facet Wu, Huilu
Jia, Fei
Kong, Jin
Kou, Fan
Yuan, Jingkun
author_sort Wu, Huilu
collection PubMed
description In the title complex, [Mn(C(4)H(5)O(2))(C(27)H(27)N(7))(C(3)H(7)NO)]ClO(4)·C(3)H(7)NO, the Mn(II) ion is seven-coordinated in a distorted monocapped trigonal-prismatic geometry formed by a tetra­dentate tris­(1-methyl-1H-benzimidazol-2-ylmeth­yl)amine mol­ecule, a bidentate 2-methacrylate anion and a dimethyl­formamide mol­ecule. The methyl groups of the coordinated dimethyl­formamide mol­ecule and the perchlorate anions are disordered over two positions with occupancy factors of 0.640 (8) and 0.360 (8).
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spelling pubmed-29833342010-12-30 (Dimethyl­formamide)(2-methyl­propen­oato)[tris­(1-methyl-1H-benzimidazol-2-ylmeth­yl)amine]­manganese(II) perchlorate dimethyl­formamide solvate Wu, Huilu Jia, Fei Kong, Jin Kou, Fan Yuan, Jingkun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(4)H(5)O(2))(C(27)H(27)N(7))(C(3)H(7)NO)]ClO(4)·C(3)H(7)NO, the Mn(II) ion is seven-coordinated in a distorted monocapped trigonal-prismatic geometry formed by a tetra­dentate tris­(1-methyl-1H-benzimidazol-2-ylmeth­yl)amine mol­ecule, a bidentate 2-methacrylate anion and a dimethyl­formamide mol­ecule. The methyl groups of the coordinated dimethyl­formamide mol­ecule and the perchlorate anions are disordered over two positions with occupancy factors of 0.640 (8) and 0.360 (8). International Union of Crystallography 2010-09-18 /pmc/articles/PMC2983334/ /pubmed/21587415 http://dx.doi.org/10.1107/S1600536810036457 Text en © Wu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Huilu
Jia, Fei
Kong, Jin
Kou, Fan
Yuan, Jingkun
(Dimethyl­formamide)(2-methyl­propen­oato)[tris­(1-methyl-1H-benzimidazol-2-ylmeth­yl)amine]­manganese(II) perchlorate dimethyl­formamide solvate
title (Dimethyl­formamide)(2-methyl­propen­oato)[tris­(1-methyl-1H-benzimidazol-2-ylmeth­yl)amine]­manganese(II) perchlorate dimethyl­formamide solvate
title_full (Dimethyl­formamide)(2-methyl­propen­oato)[tris­(1-methyl-1H-benzimidazol-2-ylmeth­yl)amine]­manganese(II) perchlorate dimethyl­formamide solvate
title_fullStr (Dimethyl­formamide)(2-methyl­propen­oato)[tris­(1-methyl-1H-benzimidazol-2-ylmeth­yl)amine]­manganese(II) perchlorate dimethyl­formamide solvate
title_full_unstemmed (Dimethyl­formamide)(2-methyl­propen­oato)[tris­(1-methyl-1H-benzimidazol-2-ylmeth­yl)amine]­manganese(II) perchlorate dimethyl­formamide solvate
title_short (Dimethyl­formamide)(2-methyl­propen­oato)[tris­(1-methyl-1H-benzimidazol-2-ylmeth­yl)amine]­manganese(II) perchlorate dimethyl­formamide solvate
title_sort (dimethyl­formamide)(2-methyl­propen­oato)[tris­(1-methyl-1h-benzimidazol-2-ylmeth­yl)amine]­manganese(ii) perchlorate dimethyl­formamide solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983334/
https://www.ncbi.nlm.nih.gov/pubmed/21587415
http://dx.doi.org/10.1107/S1600536810036457
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