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Poly[bis(μ(3)-thio­cyanato-κ(3) N:S:S′)(μ(2)-thio­cyanato-κ(2) N:S)(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)silver(I)]

The title compound, [AgCd(NCS)(3)(C(22)H(17)N(3))](n), is a hetero­atom ribbon coordination polymer. The central Cd atom is chelated by the 4′-p-tolyl-2,2′:6′,2′′-terpyridine ligand and is coordinated by the N atoms of three thio­cyanate ions in an octa­hedral geometry whereas the Ag atom is coordin...

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Detalles Bibliográficos
Autores principales: Li, Yu-Yang, Wei, Zhen-Hong, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983338/
https://www.ncbi.nlm.nih.gov/pubmed/21587450
http://dx.doi.org/10.1107/S160053681003744X
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author Li, Yu-Yang
Wei, Zhen-Hong
Ng, Seik Weng
author_facet Li, Yu-Yang
Wei, Zhen-Hong
Ng, Seik Weng
author_sort Li, Yu-Yang
collection PubMed
description The title compound, [AgCd(NCS)(3)(C(22)H(17)N(3))](n), is a hetero­atom ribbon coordination polymer. The central Cd atom is chelated by the 4′-p-tolyl-2,2′:6′,2′′-terpyridine ligand and is coordinated by the N atoms of three thio­cyanate ions in an octa­hedral geometry whereas the Ag atom is coordinated by the four S atoms of four thio­cyanate ions in a distorted tetra­hedral geometry. Of the three thio­cyanate ions, one functions in a μ (2)-bridging mode and two in a μ (3)-bridging mode. The ribbon coordination polymer propagates along the a-axis.
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spelling pubmed-29833382010-12-30 Poly[bis(μ(3)-thio­cyanato-κ(3) N:S:S′)(μ(2)-thio­cyanato-κ(2) N:S)(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)silver(I)] Li, Yu-Yang Wei, Zhen-Hong Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [AgCd(NCS)(3)(C(22)H(17)N(3))](n), is a hetero­atom ribbon coordination polymer. The central Cd atom is chelated by the 4′-p-tolyl-2,2′:6′,2′′-terpyridine ligand and is coordinated by the N atoms of three thio­cyanate ions in an octa­hedral geometry whereas the Ag atom is coordinated by the four S atoms of four thio­cyanate ions in a distorted tetra­hedral geometry. Of the three thio­cyanate ions, one functions in a μ (2)-bridging mode and two in a μ (3)-bridging mode. The ribbon coordination polymer propagates along the a-axis. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983338/ /pubmed/21587450 http://dx.doi.org/10.1107/S160053681003744X Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Yu-Yang
Wei, Zhen-Hong
Ng, Seik Weng
Poly[bis(μ(3)-thio­cyanato-κ(3) N:S:S′)(μ(2)-thio­cyanato-κ(2) N:S)(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)silver(I)]
title Poly[bis(μ(3)-thio­cyanato-κ(3) N:S:S′)(μ(2)-thio­cyanato-κ(2) N:S)(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)silver(I)]
title_full Poly[bis(μ(3)-thio­cyanato-κ(3) N:S:S′)(μ(2)-thio­cyanato-κ(2) N:S)(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)silver(I)]
title_fullStr Poly[bis(μ(3)-thio­cyanato-κ(3) N:S:S′)(μ(2)-thio­cyanato-κ(2) N:S)(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)silver(I)]
title_full_unstemmed Poly[bis(μ(3)-thio­cyanato-κ(3) N:S:S′)(μ(2)-thio­cyanato-κ(2) N:S)(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)silver(I)]
title_short Poly[bis(μ(3)-thio­cyanato-κ(3) N:S:S′)(μ(2)-thio­cyanato-κ(2) N:S)(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)silver(I)]
title_sort poly[bis(μ(3)-thio­cyanato-κ(3) n:s:s′)(μ(2)-thio­cyanato-κ(2) n:s)(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ(3) n,n′,n′′)cadmium(ii)silver(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983338/
https://www.ncbi.nlm.nih.gov/pubmed/21587450
http://dx.doi.org/10.1107/S160053681003744X
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