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Poly[bis(μ(3)-thiocyanato-κ(3) N:S:S′)(μ(2)-thiocyanato-κ(2) N:S)(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)silver(I)]
The title compound, [AgCd(NCS)(3)(C(22)H(17)N(3))](n), is a heteroatom ribbon coordination polymer. The central Cd atom is chelated by the 4′-p-tolyl-2,2′:6′,2′′-terpyridine ligand and is coordinated by the N atoms of three thiocyanate ions in an octahedral geometry whereas the Ag atom is coordin...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983338/ https://www.ncbi.nlm.nih.gov/pubmed/21587450 http://dx.doi.org/10.1107/S160053681003744X |
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author | Li, Yu-Yang Wei, Zhen-Hong Ng, Seik Weng |
author_facet | Li, Yu-Yang Wei, Zhen-Hong Ng, Seik Weng |
author_sort | Li, Yu-Yang |
collection | PubMed |
description | The title compound, [AgCd(NCS)(3)(C(22)H(17)N(3))](n), is a heteroatom ribbon coordination polymer. The central Cd atom is chelated by the 4′-p-tolyl-2,2′:6′,2′′-terpyridine ligand and is coordinated by the N atoms of three thiocyanate ions in an octahedral geometry whereas the Ag atom is coordinated by the four S atoms of four thiocyanate ions in a distorted tetrahedral geometry. Of the three thiocyanate ions, one functions in a μ (2)-bridging mode and two in a μ (3)-bridging mode. The ribbon coordination polymer propagates along the a-axis. |
format | Text |
id | pubmed-2983338 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29833382010-12-30 Poly[bis(μ(3)-thiocyanato-κ(3) N:S:S′)(μ(2)-thiocyanato-κ(2) N:S)(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)silver(I)] Li, Yu-Yang Wei, Zhen-Hong Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [AgCd(NCS)(3)(C(22)H(17)N(3))](n), is a heteroatom ribbon coordination polymer. The central Cd atom is chelated by the 4′-p-tolyl-2,2′:6′,2′′-terpyridine ligand and is coordinated by the N atoms of three thiocyanate ions in an octahedral geometry whereas the Ag atom is coordinated by the four S atoms of four thiocyanate ions in a distorted tetrahedral geometry. Of the three thiocyanate ions, one functions in a μ (2)-bridging mode and two in a μ (3)-bridging mode. The ribbon coordination polymer propagates along the a-axis. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983338/ /pubmed/21587450 http://dx.doi.org/10.1107/S160053681003744X Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Yu-Yang Wei, Zhen-Hong Ng, Seik Weng Poly[bis(μ(3)-thiocyanato-κ(3) N:S:S′)(μ(2)-thiocyanato-κ(2) N:S)(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)silver(I)] |
title | Poly[bis(μ(3)-thiocyanato-κ(3)
N:S:S′)(μ(2)-thiocyanato-κ(2)
N:S)(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)cadmium(II)silver(I)] |
title_full | Poly[bis(μ(3)-thiocyanato-κ(3)
N:S:S′)(μ(2)-thiocyanato-κ(2)
N:S)(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)cadmium(II)silver(I)] |
title_fullStr | Poly[bis(μ(3)-thiocyanato-κ(3)
N:S:S′)(μ(2)-thiocyanato-κ(2)
N:S)(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)cadmium(II)silver(I)] |
title_full_unstemmed | Poly[bis(μ(3)-thiocyanato-κ(3)
N:S:S′)(μ(2)-thiocyanato-κ(2)
N:S)(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)cadmium(II)silver(I)] |
title_short | Poly[bis(μ(3)-thiocyanato-κ(3)
N:S:S′)(μ(2)-thiocyanato-κ(2)
N:S)(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)cadmium(II)silver(I)] |
title_sort | poly[bis(μ(3)-thiocyanato-κ(3)
n:s:s′)(μ(2)-thiocyanato-κ(2)
n:s)(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ(3)
n,n′,n′′)cadmium(ii)silver(i)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983338/ https://www.ncbi.nlm.nih.gov/pubmed/21587450 http://dx.doi.org/10.1107/S160053681003744X |
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