Bis(9-amino­acridinium) bis­(pyridine-2,6-dicarboxyl­ato)cuprate(II) trihydrate

The asymmetric unit of the title compound, (C(13)H(11)N(2))(2)[Cu(C(7)H(3)NO(4))(2)]·3H(2)O or (9-aminoAcr)[Cu(pydc)(2)]·3H(2)O, contains a Cu(pydc)(2) (pydc = pyridine-2,6-dicarboxyl­ate) anion, two protonated 9-amino­acridine (9-aminoAcr)(+) counter-ions and three uncoordinated water mol­ecules. T...

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Autores principales: Aghabozorg, Hossein, Ahmadvand, Shabnam, Mirzaei, Masoud, Khavasi, Hamid Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983340/
https://www.ncbi.nlm.nih.gov/pubmed/21587453
http://dx.doi.org/10.1107/S1600536810037499
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author Aghabozorg, Hossein
Ahmadvand, Shabnam
Mirzaei, Masoud
Khavasi, Hamid Reza
author_facet Aghabozorg, Hossein
Ahmadvand, Shabnam
Mirzaei, Masoud
Khavasi, Hamid Reza
author_sort Aghabozorg, Hossein
collection PubMed
description The asymmetric unit of the title compound, (C(13)H(11)N(2))(2)[Cu(C(7)H(3)NO(4))(2)]·3H(2)O or (9-aminoAcr)[Cu(pydc)(2)]·3H(2)O, contains a Cu(pydc)(2) (pydc = pyridine-2,6-dicarboxyl­ate) anion, two protonated 9-amino­acridine (9-aminoAcr)(+) counter-ions and three uncoordinated water mol­ecules. The anion contains a six-coordinated Cu(II) atom within a distorted octa­hedral geometry. Non-covalent inter­actions i.e. N—H⋯O and O—H⋯O hydrogen bonds and inter­molecular π–π contacts between the pyridine rings [centroid–centroid distance = 3.7773 (13) Å] and acridine rings [centroid–centroid distance = 3.4897 (13), 3.7784 (14) and 3.8627 (15) Å] result in the formation of a three-dimensional network.
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spelling pubmed-29833402010-12-30 Bis(9-amino­acridinium) bis­(pyridine-2,6-dicarboxyl­ato)cuprate(II) trihydrate Aghabozorg, Hossein Ahmadvand, Shabnam Mirzaei, Masoud Khavasi, Hamid Reza Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(13)H(11)N(2))(2)[Cu(C(7)H(3)NO(4))(2)]·3H(2)O or (9-aminoAcr)[Cu(pydc)(2)]·3H(2)O, contains a Cu(pydc)(2) (pydc = pyridine-2,6-dicarboxyl­ate) anion, two protonated 9-amino­acridine (9-aminoAcr)(+) counter-ions and three uncoordinated water mol­ecules. The anion contains a six-coordinated Cu(II) atom within a distorted octa­hedral geometry. Non-covalent inter­actions i.e. N—H⋯O and O—H⋯O hydrogen bonds and inter­molecular π–π contacts between the pyridine rings [centroid–centroid distance = 3.7773 (13) Å] and acridine rings [centroid–centroid distance = 3.4897 (13), 3.7784 (14) and 3.8627 (15) Å] result in the formation of a three-dimensional network. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983340/ /pubmed/21587453 http://dx.doi.org/10.1107/S1600536810037499 Text en © Aghabozorg et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Aghabozorg, Hossein
Ahmadvand, Shabnam
Mirzaei, Masoud
Khavasi, Hamid Reza
Bis(9-amino­acridinium) bis­(pyridine-2,6-dicarboxyl­ato)cuprate(II) trihydrate
title Bis(9-amino­acridinium) bis­(pyridine-2,6-dicarboxyl­ato)cuprate(II) trihydrate
title_full Bis(9-amino­acridinium) bis­(pyridine-2,6-dicarboxyl­ato)cuprate(II) trihydrate
title_fullStr Bis(9-amino­acridinium) bis­(pyridine-2,6-dicarboxyl­ato)cuprate(II) trihydrate
title_full_unstemmed Bis(9-amino­acridinium) bis­(pyridine-2,6-dicarboxyl­ato)cuprate(II) trihydrate
title_short Bis(9-amino­acridinium) bis­(pyridine-2,6-dicarboxyl­ato)cuprate(II) trihydrate
title_sort bis(9-amino­acridinium) bis­(pyridine-2,6-dicarboxyl­ato)cuprate(ii) trihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983340/
https://www.ncbi.nlm.nih.gov/pubmed/21587453
http://dx.doi.org/10.1107/S1600536810037499
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AT mirzaeimasoud bis9aminoacridiniumbispyridine26dicarboxylatocuprateiitrihydrate
AT khavasihamidreza bis9aminoacridiniumbispyridine26dicarboxylatocuprateiitrihydrate

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