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N-(Diethylcarbamothioyl)-4-nitrobenzamide
In the title compound, C(12)H(15)N(3)O(3)S, the 4-nitro and carbonyl groups are nearly coplanar with the benzene ring [C—C—N—O = −175.72 (14) and C—C—C—O = 172.75 (14)°]. The diethylcarbamothioyl group is twisted significantly from the plane of the benzene ring [C—N—C—N = −89.79 (15)°] with the S a...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983343/ https://www.ncbi.nlm.nih.gov/pubmed/21587569 http://dx.doi.org/10.1107/S1600536810036366 |
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author | Saeed, Sohail Rashid, Naghmana Jasinski, Jerry P. Butcher, Ray J. Rizwan, Hussain |
author_facet | Saeed, Sohail Rashid, Naghmana Jasinski, Jerry P. Butcher, Ray J. Rizwan, Hussain |
author_sort | Saeed, Sohail |
collection | PubMed |
description | In the title compound, C(12)H(15)N(3)O(3)S, the 4-nitro and carbonyl groups are nearly coplanar with the benzene ring [C—C—N—O = −175.72 (14) and C—C—C—O = 172.75 (14)°]. The diethylcarbamothioyl group is twisted significantly from the plane of the benzene ring [C—N—C—N = −89.79 (15)°] with the S atom pointing away from each of these groups [C—N—C—S = 91.12 (14)°]. In the crystal, an intermolecular N—H⋯O hydrogen bond, which forms an infinite polymeric chain along the c axis, and weak C—H⋯O and C—H⋯S hydrogen bonds are observed. |
format | Text |
id | pubmed-2983343 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29833432010-12-30 N-(Diethylcarbamothioyl)-4-nitrobenzamide Saeed, Sohail Rashid, Naghmana Jasinski, Jerry P. Butcher, Ray J. Rizwan, Hussain Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(15)N(3)O(3)S, the 4-nitro and carbonyl groups are nearly coplanar with the benzene ring [C—C—N—O = −175.72 (14) and C—C—C—O = 172.75 (14)°]. The diethylcarbamothioyl group is twisted significantly from the plane of the benzene ring [C—N—C—N = −89.79 (15)°] with the S atom pointing away from each of these groups [C—N—C—S = 91.12 (14)°]. In the crystal, an intermolecular N—H⋯O hydrogen bond, which forms an infinite polymeric chain along the c axis, and weak C—H⋯O and C—H⋯S hydrogen bonds are observed. International Union of Crystallography 2010-09-18 /pmc/articles/PMC2983343/ /pubmed/21587569 http://dx.doi.org/10.1107/S1600536810036366 Text en © Saeed et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Saeed, Sohail Rashid, Naghmana Jasinski, Jerry P. Butcher, Ray J. Rizwan, Hussain N-(Diethylcarbamothioyl)-4-nitrobenzamide |
title |
N-(Diethylcarbamothioyl)-4-nitrobenzamide |
title_full |
N-(Diethylcarbamothioyl)-4-nitrobenzamide |
title_fullStr |
N-(Diethylcarbamothioyl)-4-nitrobenzamide |
title_full_unstemmed |
N-(Diethylcarbamothioyl)-4-nitrobenzamide |
title_short |
N-(Diethylcarbamothioyl)-4-nitrobenzamide |
title_sort | n-(diethylcarbamothioyl)-4-nitrobenzamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983343/ https://www.ncbi.nlm.nih.gov/pubmed/21587569 http://dx.doi.org/10.1107/S1600536810036366 |
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