Dihydro­myricetin hexa­acetate

In the title compound, C(27)H(24)O(14), also known as 2,3-di­acetoxy-5-[(2RS,3RS)-3,5,7-triacetoxy-4-oxochromen-2-yl]phenyl acetate, the heterocyclic ring adopts a distorted half-chair conformation, with two C atoms displaced by 0.1775 (16) and −0.5950 (16) Å from the mean plane of the other four at...

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Detalles Bibliográficos
Autores principales: Li, Wei, Bhadbhade, Mohan, Hook, James, Zhao, Jian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983347/
https://www.ncbi.nlm.nih.gov/pubmed/21587600
http://dx.doi.org/10.1107/S1600536810037578
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author Li, Wei
Bhadbhade, Mohan
Hook, James
Zhao, Jian
author_facet Li, Wei
Bhadbhade, Mohan
Hook, James
Zhao, Jian
author_sort Li, Wei
collection PubMed
description In the title compound, C(27)H(24)O(14), also known as 2,3-di­acetoxy-5-[(2RS,3RS)-3,5,7-triacetoxy-4-oxochromen-2-yl]phenyl acetate, the heterocyclic ring adopts a distorted half-chair conformation, with two C atoms displaced by 0.1775 (16) and −0.5950 (16) Å from the mean plane of the other four atoms. The dihedral angle between the aromatic rings is 57.81 (8)°. In the crystal, the mol­ecules inter­act by C—H⋯O bonds, aromatic π–π stacking [centroid–centroid separation = 3.6206 (9) Å] and C—H⋯π inter­actions.
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spelling pubmed-29833472010-12-30 Dihydro­myricetin hexa­acetate Li, Wei Bhadbhade, Mohan Hook, James Zhao, Jian Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(27)H(24)O(14), also known as 2,3-di­acetoxy-5-[(2RS,3RS)-3,5,7-triacetoxy-4-oxochromen-2-yl]phenyl acetate, the heterocyclic ring adopts a distorted half-chair conformation, with two C atoms displaced by 0.1775 (16) and −0.5950 (16) Å from the mean plane of the other four atoms. The dihedral angle between the aromatic rings is 57.81 (8)°. In the crystal, the mol­ecules inter­act by C—H⋯O bonds, aromatic π–π stacking [centroid–centroid separation = 3.6206 (9) Å] and C—H⋯π inter­actions. International Union of Crystallography 2010-09-25 /pmc/articles/PMC2983347/ /pubmed/21587600 http://dx.doi.org/10.1107/S1600536810037578 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Wei
Bhadbhade, Mohan
Hook, James
Zhao, Jian
Dihydro­myricetin hexa­acetate
title Dihydro­myricetin hexa­acetate
title_full Dihydro­myricetin hexa­acetate
title_fullStr Dihydro­myricetin hexa­acetate
title_full_unstemmed Dihydro­myricetin hexa­acetate
title_short Dihydro­myricetin hexa­acetate
title_sort dihydro­myricetin hexa­acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983347/
https://www.ncbi.nlm.nih.gov/pubmed/21587600
http://dx.doi.org/10.1107/S1600536810037578
work_keys_str_mv AT liwei dihydromyricetinhexaacetate
AT bhadbhademohan dihydromyricetinhexaacetate
AT hookjames dihydromyricetinhexaacetate
AT zhaojian dihydromyricetinhexaacetate

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