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catena-Poly[[[tetra­aqua­cadmium(II)]-μ-3,3′-[p-phenyl­enebis(oxymethyl­ene)]bis­(1-pyridinioacetate)] dinitrate hemihydrate]

In the title polymeric coordination complex, {[Cd(C(22)H(20)N(2)O(6))(H(2)O)(4)](NO(3))(2)·0.5H(2)O}(n), obtained from the self-assembly of the flexible double betaine 3,3′-[p-phenyl­enebis(oxymethyl­ene)]bis­(1-pyridinioacetate) with cadmium nitrate, both the octa­hedrally coordinated Cd(II) cation...

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Detalles Bibliográficos
Autores principales: Lian, Hong-Lei, Pan, Wei-Cheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983349/
https://www.ncbi.nlm.nih.gov/pubmed/21587409
http://dx.doi.org/10.1107/S1600536810036317
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author Lian, Hong-Lei
Pan, Wei-Cheng
author_facet Lian, Hong-Lei
Pan, Wei-Cheng
author_sort Lian, Hong-Lei
collection PubMed
description In the title polymeric coordination complex, {[Cd(C(22)H(20)N(2)O(6))(H(2)O)(4)](NO(3))(2)·0.5H(2)O}(n), obtained from the self-assembly of the flexible double betaine 3,3′-[p-phenyl­enebis(oxymethyl­ene)]bis­(1-pyridinioacetate) with cadmium nitrate, both the octa­hedrally coordinated Cd(II) cation and the substituted betaine ligand lie on inversion centres. The chains constructed through the trans-related acetate groups of the ligand are inter-connected via O—H⋯O hydrogen bonds involving coordinated aqua ligands, the nitrate anions and the partial-occupancy (0.25) water mol­ecule of solvation, forming a three-dimensional structure.
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spelling pubmed-29833492010-12-30 catena-Poly[[[tetra­aqua­cadmium(II)]-μ-3,3′-[p-phenyl­enebis(oxymethyl­ene)]bis­(1-pyridinioacetate)] dinitrate hemihydrate] Lian, Hong-Lei Pan, Wei-Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymeric coordination complex, {[Cd(C(22)H(20)N(2)O(6))(H(2)O)(4)](NO(3))(2)·0.5H(2)O}(n), obtained from the self-assembly of the flexible double betaine 3,3′-[p-phenyl­enebis(oxymethyl­ene)]bis­(1-pyridinioacetate) with cadmium nitrate, both the octa­hedrally coordinated Cd(II) cation and the substituted betaine ligand lie on inversion centres. The chains constructed through the trans-related acetate groups of the ligand are inter-connected via O—H⋯O hydrogen bonds involving coordinated aqua ligands, the nitrate anions and the partial-occupancy (0.25) water mol­ecule of solvation, forming a three-dimensional structure. International Union of Crystallography 2010-09-15 /pmc/articles/PMC2983349/ /pubmed/21587409 http://dx.doi.org/10.1107/S1600536810036317 Text en © Lian and Pan 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lian, Hong-Lei
Pan, Wei-Cheng
catena-Poly[[[tetra­aqua­cadmium(II)]-μ-3,3′-[p-phenyl­enebis(oxymethyl­ene)]bis­(1-pyridinioacetate)] dinitrate hemihydrate]
title catena-Poly[[[tetra­aqua­cadmium(II)]-μ-3,3′-[p-phenyl­enebis(oxymethyl­ene)]bis­(1-pyridinioacetate)] dinitrate hemihydrate]
title_full catena-Poly[[[tetra­aqua­cadmium(II)]-μ-3,3′-[p-phenyl­enebis(oxymethyl­ene)]bis­(1-pyridinioacetate)] dinitrate hemihydrate]
title_fullStr catena-Poly[[[tetra­aqua­cadmium(II)]-μ-3,3′-[p-phenyl­enebis(oxymethyl­ene)]bis­(1-pyridinioacetate)] dinitrate hemihydrate]
title_full_unstemmed catena-Poly[[[tetra­aqua­cadmium(II)]-μ-3,3′-[p-phenyl­enebis(oxymethyl­ene)]bis­(1-pyridinioacetate)] dinitrate hemihydrate]
title_short catena-Poly[[[tetra­aqua­cadmium(II)]-μ-3,3′-[p-phenyl­enebis(oxymethyl­ene)]bis­(1-pyridinioacetate)] dinitrate hemihydrate]
title_sort catena-poly[[[tetra­aqua­cadmium(ii)]-μ-3,3′-[p-phenyl­enebis(oxymethyl­ene)]bis­(1-pyridinioacetate)] dinitrate hemihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983349/
https://www.ncbi.nlm.nih.gov/pubmed/21587409
http://dx.doi.org/10.1107/S1600536810036317
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AT panweicheng catenapolytetraaquacadmiumiim33pphenylenebisoxymethylenebis1pyridinioacetatedinitratehemihydrate