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catena-Poly[[[tetraaquacadmium(II)]-μ-3,3′-[p-phenylenebis(oxymethylene)]bis(1-pyridinioacetate)] dinitrate hemihydrate]
In the title polymeric coordination complex, {[Cd(C(22)H(20)N(2)O(6))(H(2)O)(4)](NO(3))(2)·0.5H(2)O}(n), obtained from the self-assembly of the flexible double betaine 3,3′-[p-phenylenebis(oxymethylene)]bis(1-pyridinioacetate) with cadmium nitrate, both the octahedrally coordinated Cd(II) cation...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983349/ https://www.ncbi.nlm.nih.gov/pubmed/21587409 http://dx.doi.org/10.1107/S1600536810036317 |
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author | Lian, Hong-Lei Pan, Wei-Cheng |
author_facet | Lian, Hong-Lei Pan, Wei-Cheng |
author_sort | Lian, Hong-Lei |
collection | PubMed |
description | In the title polymeric coordination complex, {[Cd(C(22)H(20)N(2)O(6))(H(2)O)(4)](NO(3))(2)·0.5H(2)O}(n), obtained from the self-assembly of the flexible double betaine 3,3′-[p-phenylenebis(oxymethylene)]bis(1-pyridinioacetate) with cadmium nitrate, both the octahedrally coordinated Cd(II) cation and the substituted betaine ligand lie on inversion centres. The chains constructed through the trans-related acetate groups of the ligand are inter-connected via O—H⋯O hydrogen bonds involving coordinated aqua ligands, the nitrate anions and the partial-occupancy (0.25) water molecule of solvation, forming a three-dimensional structure. |
format | Text |
id | pubmed-2983349 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29833492010-12-30 catena-Poly[[[tetraaquacadmium(II)]-μ-3,3′-[p-phenylenebis(oxymethylene)]bis(1-pyridinioacetate)] dinitrate hemihydrate] Lian, Hong-Lei Pan, Wei-Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymeric coordination complex, {[Cd(C(22)H(20)N(2)O(6))(H(2)O)(4)](NO(3))(2)·0.5H(2)O}(n), obtained from the self-assembly of the flexible double betaine 3,3′-[p-phenylenebis(oxymethylene)]bis(1-pyridinioacetate) with cadmium nitrate, both the octahedrally coordinated Cd(II) cation and the substituted betaine ligand lie on inversion centres. The chains constructed through the trans-related acetate groups of the ligand are inter-connected via O—H⋯O hydrogen bonds involving coordinated aqua ligands, the nitrate anions and the partial-occupancy (0.25) water molecule of solvation, forming a three-dimensional structure. International Union of Crystallography 2010-09-15 /pmc/articles/PMC2983349/ /pubmed/21587409 http://dx.doi.org/10.1107/S1600536810036317 Text en © Lian and Pan 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Lian, Hong-Lei Pan, Wei-Cheng catena-Poly[[[tetraaquacadmium(II)]-μ-3,3′-[p-phenylenebis(oxymethylene)]bis(1-pyridinioacetate)] dinitrate hemihydrate] |
title |
catena-Poly[[[tetraaquacadmium(II)]-μ-3,3′-[p-phenylenebis(oxymethylene)]bis(1-pyridinioacetate)] dinitrate hemihydrate] |
title_full |
catena-Poly[[[tetraaquacadmium(II)]-μ-3,3′-[p-phenylenebis(oxymethylene)]bis(1-pyridinioacetate)] dinitrate hemihydrate] |
title_fullStr |
catena-Poly[[[tetraaquacadmium(II)]-μ-3,3′-[p-phenylenebis(oxymethylene)]bis(1-pyridinioacetate)] dinitrate hemihydrate] |
title_full_unstemmed |
catena-Poly[[[tetraaquacadmium(II)]-μ-3,3′-[p-phenylenebis(oxymethylene)]bis(1-pyridinioacetate)] dinitrate hemihydrate] |
title_short |
catena-Poly[[[tetraaquacadmium(II)]-μ-3,3′-[p-phenylenebis(oxymethylene)]bis(1-pyridinioacetate)] dinitrate hemihydrate] |
title_sort | catena-poly[[[tetraaquacadmium(ii)]-μ-3,3′-[p-phenylenebis(oxymethylene)]bis(1-pyridinioacetate)] dinitrate hemihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983349/ https://www.ncbi.nlm.nih.gov/pubmed/21587409 http://dx.doi.org/10.1107/S1600536810036317 |
work_keys_str_mv | AT lianhonglei catenapolytetraaquacadmiumiim33pphenylenebisoxymethylenebis1pyridinioacetatedinitratehemihydrate AT panweicheng catenapolytetraaquacadmiumiim33pphenylenebisoxymethylenebis1pyridinioacetatedinitratehemihydrate |