Cargando…
Aquabis[4-(methylsulfanyl)benzoato-κO]bis(pyridine-κN)copper(II)
In the title molecule, [Cu(C(8)H(7)O(2)S)(2)(C(5)H(5)N)(2)(H(2)O)], the Cu(II) ion is pentacoordinated in a distorted square-pyramidal geometry by two O atoms of two 4-(methylsulfanyl)benzoate anions and two N atoms of two pyridine ligands and a water O atom situated at the apical site. In the c...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983350/ https://www.ncbi.nlm.nih.gov/pubmed/21587376 http://dx.doi.org/10.1107/S1600536810035336 |
_version_ | 1782191861052473344 |
---|---|
author | Jiang, Guo-Qing Chen, Jian-Hua Wang, Miao Shi, Yu-Jun |
author_facet | Jiang, Guo-Qing Chen, Jian-Hua Wang, Miao Shi, Yu-Jun |
author_sort | Jiang, Guo-Qing |
collection | PubMed |
description | In the title molecule, [Cu(C(8)H(7)O(2)S)(2)(C(5)H(5)N)(2)(H(2)O)], the Cu(II) ion is pentacoordinated in a distorted square-pyramidal geometry by two O atoms of two 4-(methylsulfanyl)benzoate anions and two N atoms of two pyridine ligands and a water O atom situated at the apical site. In the crystal structure, O—H⋯O hydrogen bonds link molecules into chains along the b axis. |
format | Text |
id | pubmed-2983350 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29833502010-12-30 Aquabis[4-(methylsulfanyl)benzoato-κO]bis(pyridine-κN)copper(II) Jiang, Guo-Qing Chen, Jian-Hua Wang, Miao Shi, Yu-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title molecule, [Cu(C(8)H(7)O(2)S)(2)(C(5)H(5)N)(2)(H(2)O)], the Cu(II) ion is pentacoordinated in a distorted square-pyramidal geometry by two O atoms of two 4-(methylsulfanyl)benzoate anions and two N atoms of two pyridine ligands and a water O atom situated at the apical site. In the crystal structure, O—H⋯O hydrogen bonds link molecules into chains along the b axis. International Union of Crystallography 2010-09-08 /pmc/articles/PMC2983350/ /pubmed/21587376 http://dx.doi.org/10.1107/S1600536810035336 Text en © Jiang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Jiang, Guo-Qing Chen, Jian-Hua Wang, Miao Shi, Yu-Jun Aquabis[4-(methylsulfanyl)benzoato-κO]bis(pyridine-κN)copper(II) |
title | Aquabis[4-(methylsulfanyl)benzoato-κO]bis(pyridine-κN)copper(II) |
title_full | Aquabis[4-(methylsulfanyl)benzoato-κO]bis(pyridine-κN)copper(II) |
title_fullStr | Aquabis[4-(methylsulfanyl)benzoato-κO]bis(pyridine-κN)copper(II) |
title_full_unstemmed | Aquabis[4-(methylsulfanyl)benzoato-κO]bis(pyridine-κN)copper(II) |
title_short | Aquabis[4-(methylsulfanyl)benzoato-κO]bis(pyridine-κN)copper(II) |
title_sort | aquabis[4-(methylsulfanyl)benzoato-κo]bis(pyridine-κn)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983350/ https://www.ncbi.nlm.nih.gov/pubmed/21587376 http://dx.doi.org/10.1107/S1600536810035336 |
work_keys_str_mv | AT jiangguoqing aquabis4methylsulfanylbenzoatokobispyridinekncopperii AT chenjianhua aquabis4methylsulfanylbenzoatokobispyridinekncopperii AT wangmiao aquabis4methylsulfanylbenzoatokobispyridinekncopperii AT shiyujun aquabis4methylsulfanylbenzoatokobispyridinekncopperii |