catena-Poly[silver(I)-bis­[μ-bis­(diphenyl­phosphino)methane-κ(2) P:P′]-μ-thio­cyanato-κ(2) S:S-silver(I)-μ-thio­cyanato-κ(2) S:N]

The title compound, [Ag(NCS)(C(25)H(22)P(2))](n), contains two Ag(+) ions, two thio­cyanate ions and two bis­(diphenyl­phosphino)methane (dppm) ligands in the asymmetric unit. One of the thiocyanate ions bridges the two Ag(+) ions in a μ(2)-mode from its S atom and the two dppm ligands bridge the si...

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Detalles Bibliográficos
Autores principales: Song, Li-Li, Cui, Li-Na, Jin, Qiong-Hua, Zhang, Cun-Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983356/
https://www.ncbi.nlm.nih.gov/pubmed/21587389
http://dx.doi.org/10.1107/S1600536810035622
Descripción
Sumario:The title compound, [Ag(NCS)(C(25)H(22)P(2))](n), contains two Ag(+) ions, two thio­cyanate ions and two bis­(diphenyl­phosphino)methane (dppm) ligands in the asymmetric unit. One of the thiocyanate ions bridges the two Ag(+) ions in a μ(2)-mode from its S atom and the two dppm ligands bridge the silver ions in a μ(1),μ(1) mode. The remaining SCN(−) ion bridges the binuclear units via its N and S atoms, generating a one-dimensional polymer propagating in [[Image: see text]01]: the resulting AgP(2)SN and AgP(2)S(2) coordination geometries could be described as distorted tetra­hedral.

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