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catena-Poly[silver(I)-bis[μ-bis(diphenylphosphino)methane-κ(2) P:P′]-μ-thiocyanato-κ(2) S:S-silver(I)-μ-thiocyanato-κ(2) S:N]
The title compound, [Ag(NCS)(C(25)H(22)P(2))](n), contains two Ag(+) ions, two thiocyanate ions and two bis(diphenylphosphino)methane (dppm) ligands in the asymmetric unit. One of the thiocyanate ions bridges the two Ag(+) ions in a μ(2)-mode from its S atom and the two dppm ligands bridge the si...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983356/ https://www.ncbi.nlm.nih.gov/pubmed/21587389 http://dx.doi.org/10.1107/S1600536810035622 |
| _version_ | 1782191862505799680 |
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| author | Song, Li-Li Cui, Li-Na Jin, Qiong-Hua Zhang, Cun-Lin |
| author_facet | Song, Li-Li Cui, Li-Na Jin, Qiong-Hua Zhang, Cun-Lin |
| author_sort | Song, Li-Li |
| collection | PubMed |
| description | The title compound, [Ag(NCS)(C(25)H(22)P(2))](n), contains two Ag(+) ions, two thiocyanate ions and two bis(diphenylphosphino)methane (dppm) ligands in the asymmetric unit. One of the thiocyanate ions bridges the two Ag(+) ions in a μ(2)-mode from its S atom and the two dppm ligands bridge the silver ions in a μ(1),μ(1) mode. The remaining SCN(−) ion bridges the binuclear units via its N and S atoms, generating a one-dimensional polymer propagating in [[Image: see text]01]: the resulting AgP(2)SN and AgP(2)S(2) coordination geometries could be described as distorted tetrahedral. |
| format | Text |
| id | pubmed-2983356 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29833562010-12-30 catena-Poly[silver(I)-bis[μ-bis(diphenylphosphino)methane-κ(2) P:P′]-μ-thiocyanato-κ(2) S:S-silver(I)-μ-thiocyanato-κ(2) S:N] Song, Li-Li Cui, Li-Na Jin, Qiong-Hua Zhang, Cun-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ag(NCS)(C(25)H(22)P(2))](n), contains two Ag(+) ions, two thiocyanate ions and two bis(diphenylphosphino)methane (dppm) ligands in the asymmetric unit. One of the thiocyanate ions bridges the two Ag(+) ions in a μ(2)-mode from its S atom and the two dppm ligands bridge the silver ions in a μ(1),μ(1) mode. The remaining SCN(−) ion bridges the binuclear units via its N and S atoms, generating a one-dimensional polymer propagating in [[Image: see text]01]: the resulting AgP(2)SN and AgP(2)S(2) coordination geometries could be described as distorted tetrahedral. International Union of Crystallography 2010-09-11 /pmc/articles/PMC2983356/ /pubmed/21587389 http://dx.doi.org/10.1107/S1600536810035622 Text en © Song et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Song, Li-Li Cui, Li-Na Jin, Qiong-Hua Zhang, Cun-Lin catena-Poly[silver(I)-bis[μ-bis(diphenylphosphino)methane-κ(2) P:P′]-μ-thiocyanato-κ(2) S:S-silver(I)-μ-thiocyanato-κ(2) S:N] |
| title |
catena-Poly[silver(I)-bis[μ-bis(diphenylphosphino)methane-κ(2)
P:P′]-μ-thiocyanato-κ(2)
S:S-silver(I)-μ-thiocyanato-κ(2)
S:N] |
| title_full |
catena-Poly[silver(I)-bis[μ-bis(diphenylphosphino)methane-κ(2)
P:P′]-μ-thiocyanato-κ(2)
S:S-silver(I)-μ-thiocyanato-κ(2)
S:N] |
| title_fullStr |
catena-Poly[silver(I)-bis[μ-bis(diphenylphosphino)methane-κ(2)
P:P′]-μ-thiocyanato-κ(2)
S:S-silver(I)-μ-thiocyanato-κ(2)
S:N] |
| title_full_unstemmed |
catena-Poly[silver(I)-bis[μ-bis(diphenylphosphino)methane-κ(2)
P:P′]-μ-thiocyanato-κ(2)
S:S-silver(I)-μ-thiocyanato-κ(2)
S:N] |
| title_short |
catena-Poly[silver(I)-bis[μ-bis(diphenylphosphino)methane-κ(2)
P:P′]-μ-thiocyanato-κ(2)
S:S-silver(I)-μ-thiocyanato-κ(2)
S:N] |
| title_sort | catena-poly[silver(i)-bis[μ-bis(diphenylphosphino)methane-κ(2)
p:p′]-μ-thiocyanato-κ(2)
s:s-silver(i)-μ-thiocyanato-κ(2)
s:n] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983356/ https://www.ncbi.nlm.nih.gov/pubmed/21587389 http://dx.doi.org/10.1107/S1600536810035622 |
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