1-Benzoyl-3,3-dibutyl­thio­urea

The title mol­ecule, C(16)H(24)N(2)OS, is twisted about the central N(H)—C bond with a C—N(H)—C—N torsion angle of −62.67 (15)°. The carbonyl group is twisted out of the plane of the benzene ring, forming a C—C—C=O torsion angle of −25.06 (17)°. In the crystal, mol­ecules related by centres of symme...

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Detalles Bibliográficos
Autores principales: Gunasekaran, N., Karvembu, R., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983357/
https://www.ncbi.nlm.nih.gov/pubmed/21587578
http://dx.doi.org/10.1107/S1600536810037177
Descripción
Sumario:The title mol­ecule, C(16)H(24)N(2)OS, is twisted about the central N(H)—C bond with a C—N(H)—C—N torsion angle of −62.67 (15)°. The carbonyl group is twisted out of the plane of the benzene ring, forming a C—C—C=O torsion angle of −25.06 (17)°. In the crystal, mol­ecules related by centres of symmetry are linked by pairs of inter­molecular N—H⋯S hydrogen bonds, forming eight-membered {⋯HNCS}(2) synthons. These are further connected by weak via C—H⋯O contacts, forming a two-dimensional array in the bc plane.

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