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(R)-2-Methylpiperazine-1,4-diium diaquatetrachloridoferrate(II)
In the title salt, (C(5)H(14)N(2))[FeCl(4)(H(2)O)(2)], the Fe(II) cation is coordinated by four Cl(−) anions and two water molecules in a distorted octahedral geometry. The piperazine ring adopts a normal chair conformation. Intermolecular N—H⋯Cl, N—H⋯(Cl,Cl) and O—H⋯Cl hydrogen bonding is presen...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983358/ https://www.ncbi.nlm.nih.gov/pubmed/21587380 http://dx.doi.org/10.1107/S1600536810035506 |
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author | Peng, Cong-Hu Li, Yun-Peng |
author_facet | Peng, Cong-Hu Li, Yun-Peng |
author_sort | Peng, Cong-Hu |
collection | PubMed |
description | In the title salt, (C(5)H(14)N(2))[FeCl(4)(H(2)O)(2)], the Fe(II) cation is coordinated by four Cl(−) anions and two water molecules in a distorted octahedral geometry. The piperazine ring adopts a normal chair conformation. Intermolecular N—H⋯Cl, N—H⋯(Cl,Cl) and O—H⋯Cl hydrogen bonding is present in the crystal structure. |
format | Text |
id | pubmed-2983358 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29833582010-12-30 (R)-2-Methylpiperazine-1,4-diium diaquatetrachloridoferrate(II) Peng, Cong-Hu Li, Yun-Peng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, (C(5)H(14)N(2))[FeCl(4)(H(2)O)(2)], the Fe(II) cation is coordinated by four Cl(−) anions and two water molecules in a distorted octahedral geometry. The piperazine ring adopts a normal chair conformation. Intermolecular N—H⋯Cl, N—H⋯(Cl,Cl) and O—H⋯Cl hydrogen bonding is present in the crystal structure. International Union of Crystallography 2010-09-08 /pmc/articles/PMC2983358/ /pubmed/21587380 http://dx.doi.org/10.1107/S1600536810035506 Text en © Peng and Li 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Peng, Cong-Hu Li, Yun-Peng (R)-2-Methylpiperazine-1,4-diium diaquatetrachloridoferrate(II) |
title | (R)-2-Methylpiperazine-1,4-diium diaquatetrachloridoferrate(II) |
title_full | (R)-2-Methylpiperazine-1,4-diium diaquatetrachloridoferrate(II) |
title_fullStr | (R)-2-Methylpiperazine-1,4-diium diaquatetrachloridoferrate(II) |
title_full_unstemmed | (R)-2-Methylpiperazine-1,4-diium diaquatetrachloridoferrate(II) |
title_short | (R)-2-Methylpiperazine-1,4-diium diaquatetrachloridoferrate(II) |
title_sort | (r)-2-methylpiperazine-1,4-diium diaquatetrachloridoferrate(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983358/ https://www.ncbi.nlm.nih.gov/pubmed/21587380 http://dx.doi.org/10.1107/S1600536810035506 |
work_keys_str_mv | AT pengconghu r2methylpiperazine14diiumdiaquatetrachloridoferrateii AT liyunpeng r2methylpiperazine14diiumdiaquatetrachloridoferrateii |