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N′-(2-Methoxybenzylidene)acetohydrazide
In the title molecule, C(10)H(12)N(2)O(2), the acetohydrazide group is almost planar [within 0.0306 (12) Å] and forms a dihedral angle of 12.15 (14)° with the benzene ring. The methoxy group deviates from the attached benzene ring with a C—O—C—C torsion angle of 4.2 (4)°·The molecule adopts a tra...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983360/ https://www.ncbi.nlm.nih.gov/pubmed/21587637 http://dx.doi.org/10.1107/S1600536810038092 |
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author | Yu, Tie-Ming Lv, Lu-Ping |
author_facet | Yu, Tie-Ming Lv, Lu-Ping |
author_sort | Yu, Tie-Ming |
collection | PubMed |
description | In the title molecule, C(10)H(12)N(2)O(2), the acetohydrazide group is almost planar [within 0.0306 (12) Å] and forms a dihedral angle of 12.15 (14)° with the benzene ring. The methoxy group deviates from the attached benzene ring with a C—O—C—C torsion angle of 4.2 (4)°·The molecule adopts a trans configuration with respect to the C=N bond. In the crystal, molecules are linked into centrosymmetric dimers by pairs of N—H⋯O hydrogen bonds and intermolecular C—H⋯O interactions further stabilize the structure. |
format | Text |
id | pubmed-2983360 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29833602010-12-30 N′-(2-Methoxybenzylidene)acetohydrazide Yu, Tie-Ming Lv, Lu-Ping Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(10)H(12)N(2)O(2), the acetohydrazide group is almost planar [within 0.0306 (12) Å] and forms a dihedral angle of 12.15 (14)° with the benzene ring. The methoxy group deviates from the attached benzene ring with a C—O—C—C torsion angle of 4.2 (4)°·The molecule adopts a trans configuration with respect to the C=N bond. In the crystal, molecules are linked into centrosymmetric dimers by pairs of N—H⋯O hydrogen bonds and intermolecular C—H⋯O interactions further stabilize the structure. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983360/ /pubmed/21587637 http://dx.doi.org/10.1107/S1600536810038092 Text en © Yu and Lv 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Yu, Tie-Ming Lv, Lu-Ping N′-(2-Methoxybenzylidene)acetohydrazide |
title |
N′-(2-Methoxybenzylidene)acetohydrazide |
title_full |
N′-(2-Methoxybenzylidene)acetohydrazide |
title_fullStr |
N′-(2-Methoxybenzylidene)acetohydrazide |
title_full_unstemmed |
N′-(2-Methoxybenzylidene)acetohydrazide |
title_short |
N′-(2-Methoxybenzylidene)acetohydrazide |
title_sort | n′-(2-methoxybenzylidene)acetohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983360/ https://www.ncbi.nlm.nih.gov/pubmed/21587637 http://dx.doi.org/10.1107/S1600536810038092 |
work_keys_str_mv | AT yutieming n2methoxybenzylideneacetohydrazide AT lvluping n2methoxybenzylideneacetohydrazide |