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catena-Poly[(E)-4,4′-(ethene-1,2-diyl)dipyridinium [[bis(thiocyanato-κN)ferrate(II)]-di-μ-thiocyanato-κ(2) N:S;κ(2) S:N]]
In the title compound, {(C(12)H(12)N(2))[Fe(NCS)(4)]}(n), each Fe(II) cation is coordinated by four N-bonded and two S-bonded thiocyanate anions in an octahedral coordination mode. The asymmetric unit consists of one Fe(II) cation, located on a center of inversion, as well as one protonated (E)-4,...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983361/ https://www.ncbi.nlm.nih.gov/pubmed/21587404 http://dx.doi.org/10.1107/S160053681003624X |
Sumario: | In the title compound, {(C(12)H(12)N(2))[Fe(NCS)(4)]}(n), each Fe(II) cation is coordinated by four N-bonded and two S-bonded thiocyanate anions in an octahedral coordination mode. The asymmetric unit consists of one Fe(II) cation, located on a center of inversion, as well as one protonated (E)-4,4′-(ethene-1,2-diyl)dipyridinium dication and two thiocyanate anions in general positions. The crystal structure consists of Fe—(NCS)(2)—Fe chains extending along the a axis, in which two further thiocyanate anions are only terminally bonded via nitrogen. Non-coordinating (E)-4,4′-(ethene-1,2-diyl)dipyridinium cations are found between the chains. |
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