catena-Poly[[tribenzyl­tin(IV)]-μ-2-(piperidin-1-ylcarbothio­ylsulfan­yl)acetato-κ(2) O:O′]

The Sn atom in the title polymeric compound, [Sn(C(7)H(7))(3)(C(8)H(12)NO(2)S(2))](n), exists in a trans-C(3)O(2) trigonal-bipyramidal coordination environment in the two independent formula units. The carboxyl­ate moiety functions in a bridging mode, linking adjacent triorganotin cations into a lin...

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Detalles Bibliográficos
Autores principales: Keng, Thy Chun, Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983362/
https://www.ncbi.nlm.nih.gov/pubmed/21587378
http://dx.doi.org/10.1107/S1600536810035221
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author Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
author_facet Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
author_sort Keng, Thy Chun
collection PubMed
description The Sn atom in the title polymeric compound, [Sn(C(7)H(7))(3)(C(8)H(12)NO(2)S(2))](n), exists in a trans-C(3)O(2) trigonal-bipyramidal coordination environment in the two independent formula units. The carboxyl­ate moiety functions in a bridging mode, linking adjacent triorganotin cations into a linear chain running along the shortest axis of the triclinic unit cell; the repeat distance of the polymer is half the a-axial length. In one formula unit, the Sn atom is displaced out of the equatorial plane in the direction of the Sn—O(covalent) bond by 0.093 (4) Å and in the second mol­ecule, the Sn atom is displaced by 0.105 (4) Å in the same direction.
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spelling pubmed-29833622010-12-30 catena-Poly[[tribenzyl­tin(IV)]-μ-2-(piperidin-1-ylcarbothio­ylsulfan­yl)acetato-κ(2) O:O′] Keng, Thy Chun Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn atom in the title polymeric compound, [Sn(C(7)H(7))(3)(C(8)H(12)NO(2)S(2))](n), exists in a trans-C(3)O(2) trigonal-bipyramidal coordination environment in the two independent formula units. The carboxyl­ate moiety functions in a bridging mode, linking adjacent triorganotin cations into a linear chain running along the shortest axis of the triclinic unit cell; the repeat distance of the polymer is half the a-axial length. In one formula unit, the Sn atom is displaced out of the equatorial plane in the direction of the Sn—O(covalent) bond by 0.093 (4) Å and in the second mol­ecule, the Sn atom is displaced by 0.105 (4) Å in the same direction. International Union of Crystallography 2010-09-08 /pmc/articles/PMC2983362/ /pubmed/21587378 http://dx.doi.org/10.1107/S1600536810035221 Text en © Keng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
catena-Poly[[tribenzyl­tin(IV)]-μ-2-(piperidin-1-ylcarbothio­ylsulfan­yl)acetato-κ(2) O:O′]
title catena-Poly[[tribenzyl­tin(IV)]-μ-2-(piperidin-1-ylcarbothio­ylsulfan­yl)acetato-κ(2) O:O′]
title_full catena-Poly[[tribenzyl­tin(IV)]-μ-2-(piperidin-1-ylcarbothio­ylsulfan­yl)acetato-κ(2) O:O′]
title_fullStr catena-Poly[[tribenzyl­tin(IV)]-μ-2-(piperidin-1-ylcarbothio­ylsulfan­yl)acetato-κ(2) O:O′]
title_full_unstemmed catena-Poly[[tribenzyl­tin(IV)]-μ-2-(piperidin-1-ylcarbothio­ylsulfan­yl)acetato-κ(2) O:O′]
title_short catena-Poly[[tribenzyl­tin(IV)]-μ-2-(piperidin-1-ylcarbothio­ylsulfan­yl)acetato-κ(2) O:O′]
title_sort catena-poly[[tribenzyl­tin(iv)]-μ-2-(piperidin-1-ylcarbothio­ylsulfan­yl)acetato-κ(2) o:o′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983362/
https://www.ncbi.nlm.nih.gov/pubmed/21587378
http://dx.doi.org/10.1107/S1600536810035221
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AT ngseikweng catenapolytribenzyltinivm2piperidin1ylcarbothioylsulfanylacetatok2oo

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