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2-Sulfanyl­idene-1,2-dihydro­pyridine-3-carbohydrazide

All non-H atoms of the title compound, C(6)H(7)N(3)OS, which exists in the thione form, lie in a common plane (r.m.s. of non-H atoms = 0.08 Å). The amino group of the –NH–NH(2) substituent forms an intra­molecular hydrogen bond to the S atom. The terminal –NH(2) group is pyramidally coordinated; it...

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Detalles Bibliográficos
Autores principales: Mansor, Shahirah, Yehye, Wagee A., Ariffin, Azhar, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983366/
https://www.ncbi.nlm.nih.gov/pubmed/21587510
http://dx.doi.org/10.1107/S160053681003521X
Descripción
Sumario:All non-H atoms of the title compound, C(6)H(7)N(3)OS, which exists in the thione form, lie in a common plane (r.m.s. of non-H atoms = 0.08 Å). The amino group of the –NH–NH(2) substituent forms an intra­molecular hydrogen bond to the S atom. The terminal –NH(2) group is pyramidally coordinated; it forms a weak N—H⋯O and a weak N—H⋯S hydrogen bond. Furthermore, the N atom is an acceptor for a C—H⋯N contact. The amino group of the ring is a hydrogen-bond donor to the carbonyl O atom of an adjacent mol­ecule, this inter­action giving rise to a linear chain motif running along the b axis.