Cargando…
2-Sulfanylidene-1,2-dihydropyridine-3-carbohydrazide
All non-H atoms of the title compound, C(6)H(7)N(3)OS, which exists in the thione form, lie in a common plane (r.m.s. of non-H atoms = 0.08 Å). The amino group of the –NH–NH(2) substituent forms an intramolecular hydrogen bond to the S atom. The terminal –NH(2) group is pyramidally coordinated; it...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983366/ https://www.ncbi.nlm.nih.gov/pubmed/21587510 http://dx.doi.org/10.1107/S160053681003521X |
_version_ | 1782191864954224640 |
---|---|
author | Mansor, Shahirah Yehye, Wagee A. Ariffin, Azhar Ng, Seik Weng |
author_facet | Mansor, Shahirah Yehye, Wagee A. Ariffin, Azhar Ng, Seik Weng |
author_sort | Mansor, Shahirah |
collection | PubMed |
description | All non-H atoms of the title compound, C(6)H(7)N(3)OS, which exists in the thione form, lie in a common plane (r.m.s. of non-H atoms = 0.08 Å). The amino group of the –NH–NH(2) substituent forms an intramolecular hydrogen bond to the S atom. The terminal –NH(2) group is pyramidally coordinated; it forms a weak N—H⋯O and a weak N—H⋯S hydrogen bond. Furthermore, the N atom is an acceptor for a C—H⋯N contact. The amino group of the ring is a hydrogen-bond donor to the carbonyl O atom of an adjacent molecule, this interaction giving rise to a linear chain motif running along the b axis. |
format | Text |
id | pubmed-2983366 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29833662010-12-30 2-Sulfanylidene-1,2-dihydropyridine-3-carbohydrazide Mansor, Shahirah Yehye, Wagee A. Ariffin, Azhar Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers All non-H atoms of the title compound, C(6)H(7)N(3)OS, which exists in the thione form, lie in a common plane (r.m.s. of non-H atoms = 0.08 Å). The amino group of the –NH–NH(2) substituent forms an intramolecular hydrogen bond to the S atom. The terminal –NH(2) group is pyramidally coordinated; it forms a weak N—H⋯O and a weak N—H⋯S hydrogen bond. Furthermore, the N atom is an acceptor for a C—H⋯N contact. The amino group of the ring is a hydrogen-bond donor to the carbonyl O atom of an adjacent molecule, this interaction giving rise to a linear chain motif running along the b axis. International Union of Crystallography 2010-09-08 /pmc/articles/PMC2983366/ /pubmed/21587510 http://dx.doi.org/10.1107/S160053681003521X Text en © Mansor et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Mansor, Shahirah Yehye, Wagee A. Ariffin, Azhar Ng, Seik Weng 2-Sulfanylidene-1,2-dihydropyridine-3-carbohydrazide |
title | 2-Sulfanylidene-1,2-dihydropyridine-3-carbohydrazide |
title_full | 2-Sulfanylidene-1,2-dihydropyridine-3-carbohydrazide |
title_fullStr | 2-Sulfanylidene-1,2-dihydropyridine-3-carbohydrazide |
title_full_unstemmed | 2-Sulfanylidene-1,2-dihydropyridine-3-carbohydrazide |
title_short | 2-Sulfanylidene-1,2-dihydropyridine-3-carbohydrazide |
title_sort | 2-sulfanylidene-1,2-dihydropyridine-3-carbohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983366/ https://www.ncbi.nlm.nih.gov/pubmed/21587510 http://dx.doi.org/10.1107/S160053681003521X |
work_keys_str_mv | AT mansorshahirah 2sulfanylidene12dihydropyridine3carbohydrazide AT yehyewageea 2sulfanylidene12dihydropyridine3carbohydrazide AT ariffinazhar 2sulfanylidene12dihydropyridine3carbohydrazide AT ngseikweng 2sulfanylidene12dihydropyridine3carbohydrazide |