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2-Sulfanyl­idene-1,2-dihydro­pyridine-3-carbohydrazide

All non-H atoms of the title compound, C(6)H(7)N(3)OS, which exists in the thione form, lie in a common plane (r.m.s. of non-H atoms = 0.08 Å). The amino group of the –NH–NH(2) substituent forms an intra­molecular hydrogen bond to the S atom. The terminal –NH(2) group is pyramidally coordinated; it...

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Detalles Bibliográficos
Autores principales: Mansor, Shahirah, Yehye, Wagee A., Ariffin, Azhar, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983366/
https://www.ncbi.nlm.nih.gov/pubmed/21587510
http://dx.doi.org/10.1107/S160053681003521X
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author Mansor, Shahirah
Yehye, Wagee A.
Ariffin, Azhar
Ng, Seik Weng
author_facet Mansor, Shahirah
Yehye, Wagee A.
Ariffin, Azhar
Ng, Seik Weng
author_sort Mansor, Shahirah
collection PubMed
description All non-H atoms of the title compound, C(6)H(7)N(3)OS, which exists in the thione form, lie in a common plane (r.m.s. of non-H atoms = 0.08 Å). The amino group of the –NH–NH(2) substituent forms an intra­molecular hydrogen bond to the S atom. The terminal –NH(2) group is pyramidally coordinated; it forms a weak N—H⋯O and a weak N—H⋯S hydrogen bond. Furthermore, the N atom is an acceptor for a C—H⋯N contact. The amino group of the ring is a hydrogen-bond donor to the carbonyl O atom of an adjacent mol­ecule, this inter­action giving rise to a linear chain motif running along the b axis.
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spelling pubmed-29833662010-12-30 2-Sulfanyl­idene-1,2-dihydro­pyridine-3-carbohydrazide Mansor, Shahirah Yehye, Wagee A. Ariffin, Azhar Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers All non-H atoms of the title compound, C(6)H(7)N(3)OS, which exists in the thione form, lie in a common plane (r.m.s. of non-H atoms = 0.08 Å). The amino group of the –NH–NH(2) substituent forms an intra­molecular hydrogen bond to the S atom. The terminal –NH(2) group is pyramidally coordinated; it forms a weak N—H⋯O and a weak N—H⋯S hydrogen bond. Furthermore, the N atom is an acceptor for a C—H⋯N contact. The amino group of the ring is a hydrogen-bond donor to the carbonyl O atom of an adjacent mol­ecule, this inter­action giving rise to a linear chain motif running along the b axis. International Union of Crystallography 2010-09-08 /pmc/articles/PMC2983366/ /pubmed/21587510 http://dx.doi.org/10.1107/S160053681003521X Text en © Mansor et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mansor, Shahirah
Yehye, Wagee A.
Ariffin, Azhar
Ng, Seik Weng
2-Sulfanyl­idene-1,2-dihydro­pyridine-3-carbohydrazide
title 2-Sulfanyl­idene-1,2-dihydro­pyridine-3-carbohydrazide
title_full 2-Sulfanyl­idene-1,2-dihydro­pyridine-3-carbohydrazide
title_fullStr 2-Sulfanyl­idene-1,2-dihydro­pyridine-3-carbohydrazide
title_full_unstemmed 2-Sulfanyl­idene-1,2-dihydro­pyridine-3-carbohydrazide
title_short 2-Sulfanyl­idene-1,2-dihydro­pyridine-3-carbohydrazide
title_sort 2-sulfanyl­idene-1,2-dihydro­pyridine-3-carbohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983366/
https://www.ncbi.nlm.nih.gov/pubmed/21587510
http://dx.doi.org/10.1107/S160053681003521X
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