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Poly[(μ(4)-biphenyl-3,3′-dicarboxylato)bis[μ(2)-1,1′-(butane-1,4-diyl)diimidazole](μ(2)-oxalato)dimanganese(II)]
In the title coordination compound, [Mn(2)(C(14)H(8)O(4))(C(2)O(4))(C(10)H(14)N(4))(2)](n), the biphenyl-3,3′-dicarboxylate and oxalate anions, both situated on inversion centres, function in a bridging mode, linking the dinuclear Mn(II) atoms into wave-like layers. Each 1,1′-(1,4-butane-1,4-diyl)...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983367/ https://www.ncbi.nlm.nih.gov/pubmed/21587372 http://dx.doi.org/10.1107/S1600536810035269 |
Sumario: | In the title coordination compound, [Mn(2)(C(14)H(8)O(4))(C(2)O(4))(C(10)H(14)N(4))(2)](n), the biphenyl-3,3′-dicarboxylate and oxalate anions, both situated on inversion centres, function in a bridging mode, linking the dinuclear Mn(II) atoms into wave-like layers. Each 1,1′-(1,4-butane-1,4-diyl)diimidazole ligand coordinates to two Mn(II) atoms located in adjacent layers via Mn—N coordination bonds, giving a three-dimensional network. As the methylene groups can bend freely relative to each other due to the C atoms connected via single bonds, the 1,1′-(butane-1,4-diyl)diimidazole ligand forms an S-shaped conformation, which makes the void in the three-dimensional network distorted. |
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