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Poly[(μ(4)-biphenyl-3,3′-dicarboxyl­ato)bis[μ(2)-1,1′-(butane-1,4-di­yl)diimidazole](μ(2)-oxalato)dimanganese(II)]

In the title coordination compound, [Mn(2)(C(14)H(8)O(4))(C(2)O(4))(C(10)H(14)N(4))(2)](n), the biphenyl-3,3′-dicarboxyl­ate and oxalate anions, both situated on inversion centres, function in a bridging mode, linking the dinuclear Mn(II) atoms into wave-like layers. Each 1,1′-(1,4-butane-1,4-di­yl)...

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Detalles Bibliográficos
Autor principal: Zhu, Bao-Yong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983367/
https://www.ncbi.nlm.nih.gov/pubmed/21587372
http://dx.doi.org/10.1107/S1600536810035269
Descripción
Sumario:In the title coordination compound, [Mn(2)(C(14)H(8)O(4))(C(2)O(4))(C(10)H(14)N(4))(2)](n), the biphenyl-3,3′-dicarboxyl­ate and oxalate anions, both situated on inversion centres, function in a bridging mode, linking the dinuclear Mn(II) atoms into wave-like layers. Each 1,1′-(1,4-butane-1,4-di­yl)diimidazole ligand coordinates to two Mn(II) atoms located in adjacent layers via Mn—N coordination bonds, giving a three-dimensional network. As the methyl­ene groups can bend freely relative to each other due to the C atoms connected via single bonds, the 1,1′-(butane-1,4-di­yl)diimidazole ligand forms an S-shaped conformation, which makes the void in the three-dimensional network distorted.