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Poly[(μ(4)-biphenyl-3,3′-dicarboxylato)bis[μ(2)-1,1′-(butane-1,4-diyl)diimidazole](μ(2)-oxalato)dimanganese(II)]
In the title coordination compound, [Mn(2)(C(14)H(8)O(4))(C(2)O(4))(C(10)H(14)N(4))(2)](n), the biphenyl-3,3′-dicarboxylate and oxalate anions, both situated on inversion centres, function in a bridging mode, linking the dinuclear Mn(II) atoms into wave-like layers. Each 1,1′-(1,4-butane-1,4-diyl)...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983367/ https://www.ncbi.nlm.nih.gov/pubmed/21587372 http://dx.doi.org/10.1107/S1600536810035269 |
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author | Zhu, Bao-Yong |
author_facet | Zhu, Bao-Yong |
author_sort | Zhu, Bao-Yong |
collection | PubMed |
description | In the title coordination compound, [Mn(2)(C(14)H(8)O(4))(C(2)O(4))(C(10)H(14)N(4))(2)](n), the biphenyl-3,3′-dicarboxylate and oxalate anions, both situated on inversion centres, function in a bridging mode, linking the dinuclear Mn(II) atoms into wave-like layers. Each 1,1′-(1,4-butane-1,4-diyl)diimidazole ligand coordinates to two Mn(II) atoms located in adjacent layers via Mn—N coordination bonds, giving a three-dimensional network. As the methylene groups can bend freely relative to each other due to the C atoms connected via single bonds, the 1,1′-(butane-1,4-diyl)diimidazole ligand forms an S-shaped conformation, which makes the void in the three-dimensional network distorted. |
format | Text |
id | pubmed-2983367 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29833672010-12-30 Poly[(μ(4)-biphenyl-3,3′-dicarboxylato)bis[μ(2)-1,1′-(butane-1,4-diyl)diimidazole](μ(2)-oxalato)dimanganese(II)] Zhu, Bao-Yong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination compound, [Mn(2)(C(14)H(8)O(4))(C(2)O(4))(C(10)H(14)N(4))(2)](n), the biphenyl-3,3′-dicarboxylate and oxalate anions, both situated on inversion centres, function in a bridging mode, linking the dinuclear Mn(II) atoms into wave-like layers. Each 1,1′-(1,4-butane-1,4-diyl)diimidazole ligand coordinates to two Mn(II) atoms located in adjacent layers via Mn—N coordination bonds, giving a three-dimensional network. As the methylene groups can bend freely relative to each other due to the C atoms connected via single bonds, the 1,1′-(butane-1,4-diyl)diimidazole ligand forms an S-shaped conformation, which makes the void in the three-dimensional network distorted. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983367/ /pubmed/21587372 http://dx.doi.org/10.1107/S1600536810035269 Text en © Bao-Yong Zhu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhu, Bao-Yong Poly[(μ(4)-biphenyl-3,3′-dicarboxylato)bis[μ(2)-1,1′-(butane-1,4-diyl)diimidazole](μ(2)-oxalato)dimanganese(II)] |
title | Poly[(μ(4)-biphenyl-3,3′-dicarboxylato)bis[μ(2)-1,1′-(butane-1,4-diyl)diimidazole](μ(2)-oxalato)dimanganese(II)] |
title_full | Poly[(μ(4)-biphenyl-3,3′-dicarboxylato)bis[μ(2)-1,1′-(butane-1,4-diyl)diimidazole](μ(2)-oxalato)dimanganese(II)] |
title_fullStr | Poly[(μ(4)-biphenyl-3,3′-dicarboxylato)bis[μ(2)-1,1′-(butane-1,4-diyl)diimidazole](μ(2)-oxalato)dimanganese(II)] |
title_full_unstemmed | Poly[(μ(4)-biphenyl-3,3′-dicarboxylato)bis[μ(2)-1,1′-(butane-1,4-diyl)diimidazole](μ(2)-oxalato)dimanganese(II)] |
title_short | Poly[(μ(4)-biphenyl-3,3′-dicarboxylato)bis[μ(2)-1,1′-(butane-1,4-diyl)diimidazole](μ(2)-oxalato)dimanganese(II)] |
title_sort | poly[(μ(4)-biphenyl-3,3′-dicarboxylato)bis[μ(2)-1,1′-(butane-1,4-diyl)diimidazole](μ(2)-oxalato)dimanganese(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983367/ https://www.ncbi.nlm.nih.gov/pubmed/21587372 http://dx.doi.org/10.1107/S1600536810035269 |
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