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Poly[(μ(4)-biphenyl-3,3′-dicarboxyl­ato)bis[μ(2)-1,1′-(butane-1,4-di­yl)diimidazole](μ(2)-oxalato)dimanganese(II)]

In the title coordination compound, [Mn(2)(C(14)H(8)O(4))(C(2)O(4))(C(10)H(14)N(4))(2)](n), the biphenyl-3,3′-dicarboxyl­ate and oxalate anions, both situated on inversion centres, function in a bridging mode, linking the dinuclear Mn(II) atoms into wave-like layers. Each 1,1′-(1,4-butane-1,4-di­yl)...

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Detalles Bibliográficos
Autor principal: Zhu, Bao-Yong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983367/
https://www.ncbi.nlm.nih.gov/pubmed/21587372
http://dx.doi.org/10.1107/S1600536810035269
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author Zhu, Bao-Yong
author_facet Zhu, Bao-Yong
author_sort Zhu, Bao-Yong
collection PubMed
description In the title coordination compound, [Mn(2)(C(14)H(8)O(4))(C(2)O(4))(C(10)H(14)N(4))(2)](n), the biphenyl-3,3′-dicarboxyl­ate and oxalate anions, both situated on inversion centres, function in a bridging mode, linking the dinuclear Mn(II) atoms into wave-like layers. Each 1,1′-(1,4-butane-1,4-di­yl)diimidazole ligand coordinates to two Mn(II) atoms located in adjacent layers via Mn—N coordination bonds, giving a three-dimensional network. As the methyl­ene groups can bend freely relative to each other due to the C atoms connected via single bonds, the 1,1′-(butane-1,4-di­yl)diimidazole ligand forms an S-shaped conformation, which makes the void in the three-dimensional network distorted.
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spelling pubmed-29833672010-12-30 Poly[(μ(4)-biphenyl-3,3′-dicarboxyl­ato)bis[μ(2)-1,1′-(butane-1,4-di­yl)diimidazole](μ(2)-oxalato)dimanganese(II)] Zhu, Bao-Yong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination compound, [Mn(2)(C(14)H(8)O(4))(C(2)O(4))(C(10)H(14)N(4))(2)](n), the biphenyl-3,3′-dicarboxyl­ate and oxalate anions, both situated on inversion centres, function in a bridging mode, linking the dinuclear Mn(II) atoms into wave-like layers. Each 1,1′-(1,4-butane-1,4-di­yl)diimidazole ligand coordinates to two Mn(II) atoms located in adjacent layers via Mn—N coordination bonds, giving a three-dimensional network. As the methyl­ene groups can bend freely relative to each other due to the C atoms connected via single bonds, the 1,1′-(butane-1,4-di­yl)diimidazole ligand forms an S-shaped conformation, which makes the void in the three-dimensional network distorted. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983367/ /pubmed/21587372 http://dx.doi.org/10.1107/S1600536810035269 Text en © Bao-Yong Zhu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Bao-Yong
Poly[(μ(4)-biphenyl-3,3′-dicarboxyl­ato)bis[μ(2)-1,1′-(butane-1,4-di­yl)diimidazole](μ(2)-oxalato)dimanganese(II)]
title Poly[(μ(4)-biphenyl-3,3′-dicarboxyl­ato)bis[μ(2)-1,1′-(butane-1,4-di­yl)diimidazole](μ(2)-oxalato)dimanganese(II)]
title_full Poly[(μ(4)-biphenyl-3,3′-dicarboxyl­ato)bis[μ(2)-1,1′-(butane-1,4-di­yl)diimidazole](μ(2)-oxalato)dimanganese(II)]
title_fullStr Poly[(μ(4)-biphenyl-3,3′-dicarboxyl­ato)bis[μ(2)-1,1′-(butane-1,4-di­yl)diimidazole](μ(2)-oxalato)dimanganese(II)]
title_full_unstemmed Poly[(μ(4)-biphenyl-3,3′-dicarboxyl­ato)bis[μ(2)-1,1′-(butane-1,4-di­yl)diimidazole](μ(2)-oxalato)dimanganese(II)]
title_short Poly[(μ(4)-biphenyl-3,3′-dicarboxyl­ato)bis[μ(2)-1,1′-(butane-1,4-di­yl)diimidazole](μ(2)-oxalato)dimanganese(II)]
title_sort poly[(μ(4)-biphenyl-3,3′-dicarboxyl­ato)bis[μ(2)-1,1′-(butane-1,4-di­yl)diimidazole](μ(2)-oxalato)dimanganese(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983367/
https://www.ncbi.nlm.nih.gov/pubmed/21587372
http://dx.doi.org/10.1107/S1600536810035269
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