Triimidazolium tris­(pyridine-2,6-di­carboxyl­ato)dysprosate(III) trihydrate

The structure of the title compound, (C(3)N(2)H(5))(3)[Dy(C(7)H(3)NO(4))(3)]·3H(2)O, contains a mononuclear Dy(III) complex with the rare earth metal cation in a distorted tricapped trigonal–prismatic environment. The Dy(III) ion is in each case O,N,O′-chelated by three tridentate pyridine-2,6-dicar...

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Detalles Bibliográficos
Autores principales: Meng, Lingzong, Duan, Chaowen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983370/
https://www.ncbi.nlm.nih.gov/pubmed/21587433
http://dx.doi.org/10.1107/S1600536810036421
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author Meng, Lingzong
Duan, Chaowen
author_facet Meng, Lingzong
Duan, Chaowen
author_sort Meng, Lingzong
collection PubMed
description The structure of the title compound, (C(3)N(2)H(5))(3)[Dy(C(7)H(3)NO(4))(3)]·3H(2)O, contains a mononuclear Dy(III) complex with the rare earth metal cation in a distorted tricapped trigonal–prismatic environment. The Dy(III) ion is in each case O,N,O′-chelated by three tridentate pyridine-2,6-dicarboxyl­ate anions. Three protonated imidazole mol­ecules act as counter-cations and three lattice water mol­ecules are also present. Numerous N—H⋯O and O—H⋯O hydrogen bonding inter­actions, some of which are bifurcated, help to stabilize the packing of the structure.
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spelling pubmed-29833702010-12-30 Triimidazolium tris­(pyridine-2,6-di­carboxyl­ato)dysprosate(III) trihydrate Meng, Lingzong Duan, Chaowen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, (C(3)N(2)H(5))(3)[Dy(C(7)H(3)NO(4))(3)]·3H(2)O, contains a mononuclear Dy(III) complex with the rare earth metal cation in a distorted tricapped trigonal–prismatic environment. The Dy(III) ion is in each case O,N,O′-chelated by three tridentate pyridine-2,6-dicarboxyl­ate anions. Three protonated imidazole mol­ecules act as counter-cations and three lattice water mol­ecules are also present. Numerous N—H⋯O and O—H⋯O hydrogen bonding inter­actions, some of which are bifurcated, help to stabilize the packing of the structure. International Union of Crystallography 2010-09-25 /pmc/articles/PMC2983370/ /pubmed/21587433 http://dx.doi.org/10.1107/S1600536810036421 Text en © Meng and Duan 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meng, Lingzong
Duan, Chaowen
Triimidazolium tris­(pyridine-2,6-di­carboxyl­ato)dysprosate(III) trihydrate
title Triimidazolium tris­(pyridine-2,6-di­carboxyl­ato)dysprosate(III) trihydrate
title_full Triimidazolium tris­(pyridine-2,6-di­carboxyl­ato)dysprosate(III) trihydrate
title_fullStr Triimidazolium tris­(pyridine-2,6-di­carboxyl­ato)dysprosate(III) trihydrate
title_full_unstemmed Triimidazolium tris­(pyridine-2,6-di­carboxyl­ato)dysprosate(III) trihydrate
title_short Triimidazolium tris­(pyridine-2,6-di­carboxyl­ato)dysprosate(III) trihydrate
title_sort triimidazolium tris­(pyridine-2,6-di­carboxyl­ato)dysprosate(iii) trihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983370/
https://www.ncbi.nlm.nih.gov/pubmed/21587433
http://dx.doi.org/10.1107/S1600536810036421
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