A two-dimensional manganese(II) complex: poly[bis­(μ(2)-4,4′-bipyrid­yl)tetra­kis­(μ(2)-3,5-dinitro­benzoato)dimanganese(II)]

The Mn atom in the title compound, [Mn(2)(C(7)H(3)N(2)O(6))(4)(C(10)H(8)N(2))(2)](n), is six-coordinated by two N atoms and four O atoms, forming a distorted octa­hedral geometry. The Mn—O bond lengths are in the range 2.1281 (13)–2.2011 (12) Å and the Mn—N bond lengths are 2.269 (2) and 2.278 (2) Å...

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Detalles Bibliográficos
Autores principales: Wang, Jian, Li, Zhu-Lai, Xu, Xiu-Zhi, Yan, Wen-Jin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983371/
https://www.ncbi.nlm.nih.gov/pubmed/21587352
http://dx.doi.org/10.1107/S1600536810034495
Descripción
Sumario:The Mn atom in the title compound, [Mn(2)(C(7)H(3)N(2)O(6))(4)(C(10)H(8)N(2))(2)](n), is six-coordinated by two N atoms and four O atoms, forming a distorted octa­hedral geometry. The Mn—O bond lengths are in the range 2.1281 (13)–2.2011 (12) Å and the Mn—N bond lengths are 2.269 (2) and 2.278 (2) Å. Mn(II) atoms are double-bridged along the a axis by two pairs of bi-monodentate carboxyl groups, forming a double-stranded chain, while the bidentate 4,4′-bipyridine ligand bridges the Mn atom along the b axis. This results in a two-dimensional structure constructed of oblong grids with the sides of length 11.634 and 5.075 Å

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