A two-dimensional manganese(II) complex: poly[bis­(μ(2)-4,4′-bipyrid­yl)tetra­kis­(μ(2)-3,5-dinitro­benzoato)dimanganese(II)]

The Mn atom in the title compound, [Mn(2)(C(7)H(3)N(2)O(6))(4)(C(10)H(8)N(2))(2)](n), is six-coordinated by two N atoms and four O atoms, forming a distorted octa­hedral geometry. The Mn—O bond lengths are in the range 2.1281 (13)–2.2011 (12) Å and the Mn—N bond lengths are 2.269 (2) and 2.278 (2) Å...

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Detalles Bibliográficos
Autores principales: Wang, Jian, Li, Zhu-Lai, Xu, Xiu-Zhi, Yan, Wen-Jin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983371/
https://www.ncbi.nlm.nih.gov/pubmed/21587352
http://dx.doi.org/10.1107/S1600536810034495
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author Wang, Jian
Li, Zhu-Lai
Xu, Xiu-Zhi
Yan, Wen-Jin
author_facet Wang, Jian
Li, Zhu-Lai
Xu, Xiu-Zhi
Yan, Wen-Jin
author_sort Wang, Jian
collection PubMed
description The Mn atom in the title compound, [Mn(2)(C(7)H(3)N(2)O(6))(4)(C(10)H(8)N(2))(2)](n), is six-coordinated by two N atoms and four O atoms, forming a distorted octa­hedral geometry. The Mn—O bond lengths are in the range 2.1281 (13)–2.2011 (12) Å and the Mn—N bond lengths are 2.269 (2) and 2.278 (2) Å. Mn(II) atoms are double-bridged along the a axis by two pairs of bi-monodentate carboxyl groups, forming a double-stranded chain, while the bidentate 4,4′-bipyridine ligand bridges the Mn atom along the b axis. This results in a two-dimensional structure constructed of oblong grids with the sides of length 11.634 and 5.075 Å
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spelling pubmed-29833712010-12-30 A two-dimensional manganese(II) complex: poly[bis­(μ(2)-4,4′-bipyrid­yl)tetra­kis­(μ(2)-3,5-dinitro­benzoato)dimanganese(II)] Wang, Jian Li, Zhu-Lai Xu, Xiu-Zhi Yan, Wen-Jin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Mn atom in the title compound, [Mn(2)(C(7)H(3)N(2)O(6))(4)(C(10)H(8)N(2))(2)](n), is six-coordinated by two N atoms and four O atoms, forming a distorted octa­hedral geometry. The Mn—O bond lengths are in the range 2.1281 (13)–2.2011 (12) Å and the Mn—N bond lengths are 2.269 (2) and 2.278 (2) Å. Mn(II) atoms are double-bridged along the a axis by two pairs of bi-monodentate carboxyl groups, forming a double-stranded chain, while the bidentate 4,4′-bipyridine ligand bridges the Mn atom along the b axis. This results in a two-dimensional structure constructed of oblong grids with the sides of length 11.634 and 5.075 Å International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983371/ /pubmed/21587352 http://dx.doi.org/10.1107/S1600536810034495 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Jian
Li, Zhu-Lai
Xu, Xiu-Zhi
Yan, Wen-Jin
A two-dimensional manganese(II) complex: poly[bis­(μ(2)-4,4′-bipyrid­yl)tetra­kis­(μ(2)-3,5-dinitro­benzoato)dimanganese(II)]
title A two-dimensional manganese(II) complex: poly[bis­(μ(2)-4,4′-bipyrid­yl)tetra­kis­(μ(2)-3,5-dinitro­benzoato)dimanganese(II)]
title_full A two-dimensional manganese(II) complex: poly[bis­(μ(2)-4,4′-bipyrid­yl)tetra­kis­(μ(2)-3,5-dinitro­benzoato)dimanganese(II)]
title_fullStr A two-dimensional manganese(II) complex: poly[bis­(μ(2)-4,4′-bipyrid­yl)tetra­kis­(μ(2)-3,5-dinitro­benzoato)dimanganese(II)]
title_full_unstemmed A two-dimensional manganese(II) complex: poly[bis­(μ(2)-4,4′-bipyrid­yl)tetra­kis­(μ(2)-3,5-dinitro­benzoato)dimanganese(II)]
title_short A two-dimensional manganese(II) complex: poly[bis­(μ(2)-4,4′-bipyrid­yl)tetra­kis­(μ(2)-3,5-dinitro­benzoato)dimanganese(II)]
title_sort two-dimensional manganese(ii) complex: poly[bis­(μ(2)-4,4′-bipyrid­yl)tetra­kis­(μ(2)-3,5-dinitro­benzoato)dimanganese(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983371/
https://www.ncbi.nlm.nih.gov/pubmed/21587352
http://dx.doi.org/10.1107/S1600536810034495
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