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(2-Aminobenzoato-κ(2) O,O′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate
In the title salt, [Ni(C(7)H(6)NO(2))(C(16)H(36)N(4))]ClO(4)·H(2)O, the Ni(II) cation is O,O′-chelated by the benzoate anion and N,N′,N′′,N′′′-chelated by the macrocycle ligand, confering a distorted octahedral geometry on the metal atom. The complex cations, perchlorate anions and uncoordinated wa...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983378/ https://www.ncbi.nlm.nih.gov/pubmed/21587435 http://dx.doi.org/10.1107/S1600536810037116 |
| _version_ | 1782191867982512128 |
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| author | Ou, Guang-Chuan Ng, Seik Weng |
| author_facet | Ou, Guang-Chuan Ng, Seik Weng |
| author_sort | Ou, Guang-Chuan |
| collection | PubMed |
| description | In the title salt, [Ni(C(7)H(6)NO(2))(C(16)H(36)N(4))]ClO(4)·H(2)O, the Ni(II) cation is O,O′-chelated by the benzoate anion and N,N′,N′′,N′′′-chelated by the macrocycle ligand, confering a distorted octahedral geometry on the metal atom. The complex cations, perchlorate anions and uncoordinated water molecules are linked by N—H⋯O and O—H⋯O hydrogen bonds into a three-dimensional network. The perchlorate ion is disordered over two positions in a 0.554 (8):0.446 (8) ratio. |
| format | Text |
| id | pubmed-2983378 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29833782010-12-30 (2-Aminobenzoato-κ(2) O,O′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate Ou, Guang-Chuan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [Ni(C(7)H(6)NO(2))(C(16)H(36)N(4))]ClO(4)·H(2)O, the Ni(II) cation is O,O′-chelated by the benzoate anion and N,N′,N′′,N′′′-chelated by the macrocycle ligand, confering a distorted octahedral geometry on the metal atom. The complex cations, perchlorate anions and uncoordinated water molecules are linked by N—H⋯O and O—H⋯O hydrogen bonds into a three-dimensional network. The perchlorate ion is disordered over two positions in a 0.554 (8):0.446 (8) ratio. International Union of Crystallography 2010-09-25 /pmc/articles/PMC2983378/ /pubmed/21587435 http://dx.doi.org/10.1107/S1600536810037116 Text en © Ou and Ng 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ou, Guang-Chuan Ng, Seik Weng (2-Aminobenzoato-κ(2) O,O′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| title | (2-Aminobenzoato-κ(2)
O,O′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| title_full | (2-Aminobenzoato-κ(2)
O,O′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| title_fullStr | (2-Aminobenzoato-κ(2)
O,O′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| title_full_unstemmed | (2-Aminobenzoato-κ(2)
O,O′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| title_short | (2-Aminobenzoato-κ(2)
O,O′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| title_sort | (2-aminobenzoato-κ(2)
o,o′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
n,n′,n′′,n′′′)nickel(ii) perchlorate monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983378/ https://www.ncbi.nlm.nih.gov/pubmed/21587435 http://dx.doi.org/10.1107/S1600536810037116 |
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