N′-[(E)-1-(3,5-Dichloro-2-hy­droxy­phen­yl)ethyl­idene]-4-meth­oxy­benzo­hydrazide monohydrate

The title compound, C(16)H(14)Cl(2)N(2)O(3)·H(2)O, displays a trans conformation with respect to the C=N double bond. The dihedral angle between the two benzene rings is 4.98 (12)°. Intra­molecular O—H⋯N and O—H⋯O hydrogen bonds occur. The crystal structure is stabilized by inter­molecular O—H⋯O and...

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Detalles Bibliográficos
Autores principales: He, Chun-Hong, Zhang, Jian-Ping, Chang, Jian-Guo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983383/
https://www.ncbi.nlm.nih.gov/pubmed/21587638
http://dx.doi.org/10.1107/S1600536810038328
Descripción
Sumario:The title compound, C(16)H(14)Cl(2)N(2)O(3)·H(2)O, displays a trans conformation with respect to the C=N double bond. The dihedral angle between the two benzene rings is 4.98 (12)°. Intra­molecular O—H⋯N and O—H⋯O hydrogen bonds occur. The crystal structure is stabilized by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds. In addition, there are π–π inter­actions between the chemically distinct benzene rings of inversion-related mol­ecules [centroid–centroid separation = 3.715 (1) Å].

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