N′-[(E)-1-(3,5-Dichloro-2-hy­droxy­phen­yl)ethyl­idene]-4-meth­oxy­benzo­hydrazide monohydrate

The title compound, C(16)H(14)Cl(2)N(2)O(3)·H(2)O, displays a trans conformation with respect to the C=N double bond. The dihedral angle between the two benzene rings is 4.98 (12)°. Intra­molecular O—H⋯N and O—H⋯O hydrogen bonds occur. The crystal structure is stabilized by inter­molecular O—H⋯O and...

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Detalles Bibliográficos
Autores principales: He, Chun-Hong, Zhang, Jian-Ping, Chang, Jian-Guo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983383/
https://www.ncbi.nlm.nih.gov/pubmed/21587638
http://dx.doi.org/10.1107/S1600536810038328
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author He, Chun-Hong
Zhang, Jian-Ping
Chang, Jian-Guo
author_facet He, Chun-Hong
Zhang, Jian-Ping
Chang, Jian-Guo
author_sort He, Chun-Hong
collection PubMed
description The title compound, C(16)H(14)Cl(2)N(2)O(3)·H(2)O, displays a trans conformation with respect to the C=N double bond. The dihedral angle between the two benzene rings is 4.98 (12)°. Intra­molecular O—H⋯N and O—H⋯O hydrogen bonds occur. The crystal structure is stabilized by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds. In addition, there are π–π inter­actions between the chemically distinct benzene rings of inversion-related mol­ecules [centroid–centroid separation = 3.715 (1) Å].
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spelling pubmed-29833832010-12-30 N′-[(E)-1-(3,5-Dichloro-2-hy­droxy­phen­yl)ethyl­idene]-4-meth­oxy­benzo­hydrazide monohydrate He, Chun-Hong Zhang, Jian-Ping Chang, Jian-Guo Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(14)Cl(2)N(2)O(3)·H(2)O, displays a trans conformation with respect to the C=N double bond. The dihedral angle between the two benzene rings is 4.98 (12)°. Intra­molecular O—H⋯N and O—H⋯O hydrogen bonds occur. The crystal structure is stabilized by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds. In addition, there are π–π inter­actions between the chemically distinct benzene rings of inversion-related mol­ecules [centroid–centroid separation = 3.715 (1) Å]. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983383/ /pubmed/21587638 http://dx.doi.org/10.1107/S1600536810038328 Text en © He et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
He, Chun-Hong
Zhang, Jian-Ping
Chang, Jian-Guo
N′-[(E)-1-(3,5-Dichloro-2-hy­droxy­phen­yl)ethyl­idene]-4-meth­oxy­benzo­hydrazide monohydrate
title N′-[(E)-1-(3,5-Dichloro-2-hy­droxy­phen­yl)ethyl­idene]-4-meth­oxy­benzo­hydrazide monohydrate
title_full N′-[(E)-1-(3,5-Dichloro-2-hy­droxy­phen­yl)ethyl­idene]-4-meth­oxy­benzo­hydrazide monohydrate
title_fullStr N′-[(E)-1-(3,5-Dichloro-2-hy­droxy­phen­yl)ethyl­idene]-4-meth­oxy­benzo­hydrazide monohydrate
title_full_unstemmed N′-[(E)-1-(3,5-Dichloro-2-hy­droxy­phen­yl)ethyl­idene]-4-meth­oxy­benzo­hydrazide monohydrate
title_short N′-[(E)-1-(3,5-Dichloro-2-hy­droxy­phen­yl)ethyl­idene]-4-meth­oxy­benzo­hydrazide monohydrate
title_sort n′-[(e)-1-(3,5-dichloro-2-hy­droxy­phen­yl)ethyl­idene]-4-meth­oxy­benzo­hydrazide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983383/
https://www.ncbi.nlm.nih.gov/pubmed/21587638
http://dx.doi.org/10.1107/S1600536810038328
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AT zhangjianping ne135dichloro2hydroxyphenylethylidene4methoxybenzohydrazidemonohydrate
AT changjianguo ne135dichloro2hydroxyphenylethylidene4methoxybenzohydrazidemonohydrate

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