Cargando…

[μ-N,N,N′,N′-Tetra­kis­(2-pyridyl­meth­yl)pentane-1,5-diamine]­bis­[dichlorido­copper(II)] sesquihydrate

In the title dinuclear copper complex, [Cu(2)Cl(4)(C(29)H(34)N(6))]·1.5H(2)O, both Cu(II) ions are coordinated in a slightly distorted square-pyramidal environment in which the N atoms of the dipicolyl­amine group and a chloride ligand form the basal plane. The apical position is occupied by a secon...

Descripción completa

Detalles Bibliográficos
Autores principales: Bartholomä, Mark, Cheung, Hoi, Darling, Kari, Zubieta, Jon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983384/
https://www.ncbi.nlm.nih.gov/pubmed/21587361
http://dx.doi.org/10.1107/S1600536810034513
_version_ 1782191869593124864
author Bartholomä, Mark
Cheung, Hoi
Darling, Kari
Zubieta, Jon
author_facet Bartholomä, Mark
Cheung, Hoi
Darling, Kari
Zubieta, Jon
author_sort Bartholomä, Mark
collection PubMed
description In the title dinuclear copper complex, [Cu(2)Cl(4)(C(29)H(34)N(6))]·1.5H(2)O, both Cu(II) ions are coordinated in a slightly distorted square-pyramidal environment in which the N atoms of the dipicolyl­amine group and a chloride ligand form the basal plane. The apical position is occupied by a second chloride atom. The Cu—N distances involving the pyridine N atoms differ slightly from each other and the Cu—N distance involving the tertiary N atom is the longest. The apical Cu—Cl distance is elongated compared to its basal counterpart due to typical Jahn–Teller distortion. In the crystal structure, complex and water mol­ecules are linked via inter­molecular O—H⋯O and O—H⋯Cl hydrogen bonds into chains along [001]. One of the water mol­ecules was refined with half occupancy.
format Text
id pubmed-2983384
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29833842010-12-30 [μ-N,N,N′,N′-Tetra­kis­(2-pyridyl­meth­yl)pentane-1,5-diamine]­bis­[dichlorido­copper(II)] sesquihydrate Bartholomä, Mark Cheung, Hoi Darling, Kari Zubieta, Jon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear copper complex, [Cu(2)Cl(4)(C(29)H(34)N(6))]·1.5H(2)O, both Cu(II) ions are coordinated in a slightly distorted square-pyramidal environment in which the N atoms of the dipicolyl­amine group and a chloride ligand form the basal plane. The apical position is occupied by a second chloride atom. The Cu—N distances involving the pyridine N atoms differ slightly from each other and the Cu—N distance involving the tertiary N atom is the longest. The apical Cu—Cl distance is elongated compared to its basal counterpart due to typical Jahn–Teller distortion. In the crystal structure, complex and water mol­ecules are linked via inter­molecular O—H⋯O and O—H⋯Cl hydrogen bonds into chains along [001]. One of the water mol­ecules was refined with half occupancy. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983384/ /pubmed/21587361 http://dx.doi.org/10.1107/S1600536810034513 Text en © Bartholomä et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bartholomä, Mark
Cheung, Hoi
Darling, Kari
Zubieta, Jon
[μ-N,N,N′,N′-Tetra­kis­(2-pyridyl­meth­yl)pentane-1,5-diamine]­bis­[dichlorido­copper(II)] sesquihydrate
title [μ-N,N,N′,N′-Tetra­kis­(2-pyridyl­meth­yl)pentane-1,5-diamine]­bis­[dichlorido­copper(II)] sesquihydrate
title_full [μ-N,N,N′,N′-Tetra­kis­(2-pyridyl­meth­yl)pentane-1,5-diamine]­bis­[dichlorido­copper(II)] sesquihydrate
title_fullStr [μ-N,N,N′,N′-Tetra­kis­(2-pyridyl­meth­yl)pentane-1,5-diamine]­bis­[dichlorido­copper(II)] sesquihydrate
title_full_unstemmed [μ-N,N,N′,N′-Tetra­kis­(2-pyridyl­meth­yl)pentane-1,5-diamine]­bis­[dichlorido­copper(II)] sesquihydrate
title_short [μ-N,N,N′,N′-Tetra­kis­(2-pyridyl­meth­yl)pentane-1,5-diamine]­bis­[dichlorido­copper(II)] sesquihydrate
title_sort [μ-n,n,n′,n′-tetra­kis­(2-pyridyl­meth­yl)pentane-1,5-diamine]­bis­[dichlorido­copper(ii)] sesquihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983384/
https://www.ncbi.nlm.nih.gov/pubmed/21587361
http://dx.doi.org/10.1107/S1600536810034513
work_keys_str_mv AT bartholomamark mnnnntetrakis2pyridylmethylpentane15diaminebisdichloridocopperiisesquihydrate
AT cheunghoi mnnnntetrakis2pyridylmethylpentane15diaminebisdichloridocopperiisesquihydrate
AT darlingkari mnnnntetrakis2pyridylmethylpentane15diaminebisdichloridocopperiisesquihydrate
AT zubietajon mnnnntetrakis2pyridylmethylpentane15diaminebisdichloridocopperiisesquihydrate