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[μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)pentane-1,5-diamine]bis[dichloridocopper(II)] sesquihydrate
In the title dinuclear copper complex, [Cu(2)Cl(4)(C(29)H(34)N(6))]·1.5H(2)O, both Cu(II) ions are coordinated in a slightly distorted square-pyramidal environment in which the N atoms of the dipicolylamine group and a chloride ligand form the basal plane. The apical position is occupied by a secon...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983384/ https://www.ncbi.nlm.nih.gov/pubmed/21587361 http://dx.doi.org/10.1107/S1600536810034513 |
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author | Bartholomä, Mark Cheung, Hoi Darling, Kari Zubieta, Jon |
author_facet | Bartholomä, Mark Cheung, Hoi Darling, Kari Zubieta, Jon |
author_sort | Bartholomä, Mark |
collection | PubMed |
description | In the title dinuclear copper complex, [Cu(2)Cl(4)(C(29)H(34)N(6))]·1.5H(2)O, both Cu(II) ions are coordinated in a slightly distorted square-pyramidal environment in which the N atoms of the dipicolylamine group and a chloride ligand form the basal plane. The apical position is occupied by a second chloride atom. The Cu—N distances involving the pyridine N atoms differ slightly from each other and the Cu—N distance involving the tertiary N atom is the longest. The apical Cu—Cl distance is elongated compared to its basal counterpart due to typical Jahn–Teller distortion. In the crystal structure, complex and water molecules are linked via intermolecular O—H⋯O and O—H⋯Cl hydrogen bonds into chains along [001]. One of the water molecules was refined with half occupancy. |
format | Text |
id | pubmed-2983384 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29833842010-12-30 [μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)pentane-1,5-diamine]bis[dichloridocopper(II)] sesquihydrate Bartholomä, Mark Cheung, Hoi Darling, Kari Zubieta, Jon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear copper complex, [Cu(2)Cl(4)(C(29)H(34)N(6))]·1.5H(2)O, both Cu(II) ions are coordinated in a slightly distorted square-pyramidal environment in which the N atoms of the dipicolylamine group and a chloride ligand form the basal plane. The apical position is occupied by a second chloride atom. The Cu—N distances involving the pyridine N atoms differ slightly from each other and the Cu—N distance involving the tertiary N atom is the longest. The apical Cu—Cl distance is elongated compared to its basal counterpart due to typical Jahn–Teller distortion. In the crystal structure, complex and water molecules are linked via intermolecular O—H⋯O and O—H⋯Cl hydrogen bonds into chains along [001]. One of the water molecules was refined with half occupancy. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983384/ /pubmed/21587361 http://dx.doi.org/10.1107/S1600536810034513 Text en © Bartholomä et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bartholomä, Mark Cheung, Hoi Darling, Kari Zubieta, Jon [μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)pentane-1,5-diamine]bis[dichloridocopper(II)] sesquihydrate |
title | [μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)pentane-1,5-diamine]bis[dichloridocopper(II)] sesquihydrate |
title_full | [μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)pentane-1,5-diamine]bis[dichloridocopper(II)] sesquihydrate |
title_fullStr | [μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)pentane-1,5-diamine]bis[dichloridocopper(II)] sesquihydrate |
title_full_unstemmed | [μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)pentane-1,5-diamine]bis[dichloridocopper(II)] sesquihydrate |
title_short | [μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)pentane-1,5-diamine]bis[dichloridocopper(II)] sesquihydrate |
title_sort | [μ-n,n,n′,n′-tetrakis(2-pyridylmethyl)pentane-1,5-diamine]bis[dichloridocopper(ii)] sesquihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983384/ https://www.ncbi.nlm.nih.gov/pubmed/21587361 http://dx.doi.org/10.1107/S1600536810034513 |
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