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Methyl 7-oxo-12-propylamino-13-nitrodeisopropyldehydroabietate
In the title compound, C(21)H(28)N(2)O(5) (systematic name: methyl 1,4a-dimethyl-7-nitro-9-oxo-6-propylamino-1,2,3,4,4a,9,10,10a-octahydrophenanthrene-1-carboxylate) the cyclohexane ring (A) and the central cyclohexene ring (B) exist at a trans ring junction, with the two methyl groups in the...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983386/ https://www.ncbi.nlm.nih.gov/pubmed/21587581 http://dx.doi.org/10.1107/S1600536810032824 |
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author | Wang, Kai Zhang, Ye Yi, Xiang-Hui Zhang, Yong Pan, Ying-Ming |
author_facet | Wang, Kai Zhang, Ye Yi, Xiang-Hui Zhang, Yong Pan, Ying-Ming |
author_sort | Wang, Kai |
collection | PubMed |
description | In the title compound, C(21)H(28)N(2)O(5) (systematic name: methyl 1,4a-dimethyl-7-nitro-9-oxo-6-propylamino-1,2,3,4,4a,9,10,10a-octahydrophenanthrene-1-carboxylate) the cyclohexane ring (A) and the central cyclohexene ring (B) exist at a trans ring junction, with the two methyl groups in the axial positions of the six-membered rings. Ring A has a chair conformation and ring B a half-chair conformation. An intramolecular N—H⋯O hydrogen bond occurs. The crystal structure is stabilized by intermolecular C—H⋯O and N—H⋯O interactions. |
format | Text |
id | pubmed-2983386 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29833862010-12-30 Methyl 7-oxo-12-propylamino-13-nitrodeisopropyldehydroabietate Wang, Kai Zhang, Ye Yi, Xiang-Hui Zhang, Yong Pan, Ying-Ming Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(28)N(2)O(5) (systematic name: methyl 1,4a-dimethyl-7-nitro-9-oxo-6-propylamino-1,2,3,4,4a,9,10,10a-octahydrophenanthrene-1-carboxylate) the cyclohexane ring (A) and the central cyclohexene ring (B) exist at a trans ring junction, with the two methyl groups in the axial positions of the six-membered rings. Ring A has a chair conformation and ring B a half-chair conformation. An intramolecular N—H⋯O hydrogen bond occurs. The crystal structure is stabilized by intermolecular C—H⋯O and N—H⋯O interactions. International Union of Crystallography 2010-09-25 /pmc/articles/PMC2983386/ /pubmed/21587581 http://dx.doi.org/10.1107/S1600536810032824 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Wang, Kai Zhang, Ye Yi, Xiang-Hui Zhang, Yong Pan, Ying-Ming Methyl 7-oxo-12-propylamino-13-nitrodeisopropyldehydroabietate |
title | Methyl 7-oxo-12-propylamino-13-nitrodeisopropyldehydroabietate |
title_full | Methyl 7-oxo-12-propylamino-13-nitrodeisopropyldehydroabietate |
title_fullStr | Methyl 7-oxo-12-propylamino-13-nitrodeisopropyldehydroabietate |
title_full_unstemmed | Methyl 7-oxo-12-propylamino-13-nitrodeisopropyldehydroabietate |
title_short | Methyl 7-oxo-12-propylamino-13-nitrodeisopropyldehydroabietate |
title_sort | methyl 7-oxo-12-propylamino-13-nitrodeisopropyldehydroabietate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983386/ https://www.ncbi.nlm.nih.gov/pubmed/21587581 http://dx.doi.org/10.1107/S1600536810032824 |
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