catena-Poly[[[(2-pyridone-κO)silver(I)]-μ-2-pyridone-κ(2) O:O] hexa­fluorido­phosphate]

The asymmetric unit of the polymeric title salt, {[Ag(C(5)H(5)NO)(2)]PF(6)}(n), comprises an Ag(I) cation (located on a twofold axis), two 2-pyridone ligands (with distinct coordination modes), and half a PF(6) (−) anion (situated on a centre of inversion). The Ag(I) atom is in an approximately octa...

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Detalles Bibliográficos
Autores principales: Arman, Hadi D., Miller, Tyler, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983389/
https://www.ncbi.nlm.nih.gov/pubmed/21587370
http://dx.doi.org/10.1107/S1600536810035348
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author Arman, Hadi D.
Miller, Tyler
Tiekink, Edward R. T.
author_facet Arman, Hadi D.
Miller, Tyler
Tiekink, Edward R. T.
author_sort Arman, Hadi D.
collection PubMed
description The asymmetric unit of the polymeric title salt, {[Ag(C(5)H(5)NO)(2)]PF(6)}(n), comprises an Ag(I) cation (located on a twofold axis), two 2-pyridone ligands (with distinct coordination modes), and half a PF(6) (−) anion (situated on a centre of inversion). The Ag(I) atom is in an approximately octa­hedral AgO(6) coordination geometry, which is stabilized by intra­molecular N—H⋯O hydrogen bonds. The result of the bridging mode of the 2-pyridone ligand is the formation of a supra­molecular chain along the c axis; these are consolidated in the crystal by C—H⋯F inter­actions.
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spelling pubmed-29833892010-12-30 catena-Poly[[[(2-pyridone-κO)silver(I)]-μ-2-pyridone-κ(2) O:O] hexa­fluorido­phosphate] Arman, Hadi D. Miller, Tyler Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the polymeric title salt, {[Ag(C(5)H(5)NO)(2)]PF(6)}(n), comprises an Ag(I) cation (located on a twofold axis), two 2-pyridone ligands (with distinct coordination modes), and half a PF(6) (−) anion (situated on a centre of inversion). The Ag(I) atom is in an approximately octa­hedral AgO(6) coordination geometry, which is stabilized by intra­molecular N—H⋯O hydrogen bonds. The result of the bridging mode of the 2-pyridone ligand is the formation of a supra­molecular chain along the c axis; these are consolidated in the crystal by C—H⋯F inter­actions. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983389/ /pubmed/21587370 http://dx.doi.org/10.1107/S1600536810035348 Text en © Arman et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Arman, Hadi D.
Miller, Tyler
Tiekink, Edward R. T.
catena-Poly[[[(2-pyridone-κO)silver(I)]-μ-2-pyridone-κ(2) O:O] hexa­fluorido­phosphate]
title catena-Poly[[[(2-pyridone-κO)silver(I)]-μ-2-pyridone-κ(2) O:O] hexa­fluorido­phosphate]
title_full catena-Poly[[[(2-pyridone-κO)silver(I)]-μ-2-pyridone-κ(2) O:O] hexa­fluorido­phosphate]
title_fullStr catena-Poly[[[(2-pyridone-κO)silver(I)]-μ-2-pyridone-κ(2) O:O] hexa­fluorido­phosphate]
title_full_unstemmed catena-Poly[[[(2-pyridone-κO)silver(I)]-μ-2-pyridone-κ(2) O:O] hexa­fluorido­phosphate]
title_short catena-Poly[[[(2-pyridone-κO)silver(I)]-μ-2-pyridone-κ(2) O:O] hexa­fluorido­phosphate]
title_sort catena-poly[[[(2-pyridone-κo)silver(i)]-μ-2-pyridone-κ(2) o:o] hexa­fluorido­phosphate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983389/
https://www.ncbi.nlm.nih.gov/pubmed/21587370
http://dx.doi.org/10.1107/S1600536810035348
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AT millertyler catenapoly2pyridonekosilverim2pyridonek2oohexafluoridophosphate
AT tiekinkedwardrt catenapoly2pyridonekosilverim2pyridonek2oohexafluoridophosphate

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