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catena-Poly[[aquabis(pyridine-κN)copper(II)]-μ-2,2′-(p-phenylenedioxy)diacetato-κ(2) O:O′]
In the title compound, [Cu(C(10)H(8)O(6))(C(5)H(5)N)(2)(H(2)O)](n), the Cu atom is five-coordinated by two O atoms from two carboxylate groups of two different 2,2′-(p-phenylenedioxy)diacetate ligands, two N atoms from two pyridine molecules and one water O atom. The geometry is square-pyramidal...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983391/ https://www.ncbi.nlm.nih.gov/pubmed/21587426 http://dx.doi.org/10.1107/S1600536810036469 |
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author | Zhang, Xiu-Mei Li, Ya-Feng |
author_facet | Zhang, Xiu-Mei Li, Ya-Feng |
author_sort | Zhang, Xiu-Mei |
collection | PubMed |
description | In the title compound, [Cu(C(10)H(8)O(6))(C(5)H(5)N)(2)(H(2)O)](n), the Cu atom is five-coordinated by two O atoms from two carboxylate groups of two different 2,2′-(p-phenylenedioxy)diacetate ligands, two N atoms from two pyridine molecules and one water O atom. The geometry is square-pyramidal with the water O atom occupying the apical position. The carboxylate group bridges adjacent Cu atoms, forming an infinite zigzag chain extending parallel to [001]. The chains are linked into layers by O—H⋯O hydrogen bonds. The Cu and water O atoms lie on special positions of site symmetry 2. |
format | Text |
id | pubmed-2983391 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29833912010-12-30 catena-Poly[[aquabis(pyridine-κN)copper(II)]-μ-2,2′-(p-phenylenedioxy)diacetato-κ(2) O:O′] Zhang, Xiu-Mei Li, Ya-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(10)H(8)O(6))(C(5)H(5)N)(2)(H(2)O)](n), the Cu atom is five-coordinated by two O atoms from two carboxylate groups of two different 2,2′-(p-phenylenedioxy)diacetate ligands, two N atoms from two pyridine molecules and one water O atom. The geometry is square-pyramidal with the water O atom occupying the apical position. The carboxylate group bridges adjacent Cu atoms, forming an infinite zigzag chain extending parallel to [001]. The chains are linked into layers by O—H⋯O hydrogen bonds. The Cu and water O atoms lie on special positions of site symmetry 2. International Union of Crystallography 2010-09-18 /pmc/articles/PMC2983391/ /pubmed/21587426 http://dx.doi.org/10.1107/S1600536810036469 Text en © Zhang and Li 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Xiu-Mei Li, Ya-Feng catena-Poly[[aquabis(pyridine-κN)copper(II)]-μ-2,2′-(p-phenylenedioxy)diacetato-κ(2) O:O′] |
title |
catena-Poly[[aquabis(pyridine-κN)copper(II)]-μ-2,2′-(p-phenylenedioxy)diacetato-κ(2)
O:O′] |
title_full |
catena-Poly[[aquabis(pyridine-κN)copper(II)]-μ-2,2′-(p-phenylenedioxy)diacetato-κ(2)
O:O′] |
title_fullStr |
catena-Poly[[aquabis(pyridine-κN)copper(II)]-μ-2,2′-(p-phenylenedioxy)diacetato-κ(2)
O:O′] |
title_full_unstemmed |
catena-Poly[[aquabis(pyridine-κN)copper(II)]-μ-2,2′-(p-phenylenedioxy)diacetato-κ(2)
O:O′] |
title_short |
catena-Poly[[aquabis(pyridine-κN)copper(II)]-μ-2,2′-(p-phenylenedioxy)diacetato-κ(2)
O:O′] |
title_sort | catena-poly[[aquabis(pyridine-κn)copper(ii)]-μ-2,2′-(p-phenylenedioxy)diacetato-κ(2)
o:o′] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983391/ https://www.ncbi.nlm.nih.gov/pubmed/21587426 http://dx.doi.org/10.1107/S1600536810036469 |
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