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catena-Poly[[aqua­bis­(pyridine-κN)copper(II)]-μ-2,2′-(p-phenyl­enedi­oxy)diacetato-κ(2) O:O′]

In the title compound, [Cu(C(10)H(8)O(6))(C(5)H(5)N)(2)(H(2)O)](n), the Cu atom is five-coordinated by two O atoms from two carboxyl­ate groups of two different 2,2′-(p-phenyl­enedi­oxy)diacetate ligands, two N atoms from two pyridine mol­ecules and one water O atom. The geometry is square-pyramidal...

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Detalles Bibliográficos
Autores principales: Zhang, Xiu-Mei, Li, Ya-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983391/
https://www.ncbi.nlm.nih.gov/pubmed/21587426
http://dx.doi.org/10.1107/S1600536810036469
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author Zhang, Xiu-Mei
Li, Ya-Feng
author_facet Zhang, Xiu-Mei
Li, Ya-Feng
author_sort Zhang, Xiu-Mei
collection PubMed
description In the title compound, [Cu(C(10)H(8)O(6))(C(5)H(5)N)(2)(H(2)O)](n), the Cu atom is five-coordinated by two O atoms from two carboxyl­ate groups of two different 2,2′-(p-phenyl­enedi­oxy)diacetate ligands, two N atoms from two pyridine mol­ecules and one water O atom. The geometry is square-pyramidal with the water O atom occupying the apical position. The carboxyl­ate group bridges adjacent Cu atoms, forming an infinite zigzag chain extending parallel to [001]. The chains are linked into layers by O—H⋯O hydrogen bonds. The Cu and water O atoms lie on special positions of site symmetry 2.
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spelling pubmed-29833912010-12-30 catena-Poly[[aqua­bis­(pyridine-κN)copper(II)]-μ-2,2′-(p-phenyl­enedi­oxy)diacetato-κ(2) O:O′] Zhang, Xiu-Mei Li, Ya-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(10)H(8)O(6))(C(5)H(5)N)(2)(H(2)O)](n), the Cu atom is five-coordinated by two O atoms from two carboxyl­ate groups of two different 2,2′-(p-phenyl­enedi­oxy)diacetate ligands, two N atoms from two pyridine mol­ecules and one water O atom. The geometry is square-pyramidal with the water O atom occupying the apical position. The carboxyl­ate group bridges adjacent Cu atoms, forming an infinite zigzag chain extending parallel to [001]. The chains are linked into layers by O—H⋯O hydrogen bonds. The Cu and water O atoms lie on special positions of site symmetry 2. International Union of Crystallography 2010-09-18 /pmc/articles/PMC2983391/ /pubmed/21587426 http://dx.doi.org/10.1107/S1600536810036469 Text en © Zhang and Li 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Xiu-Mei
Li, Ya-Feng
catena-Poly[[aqua­bis­(pyridine-κN)copper(II)]-μ-2,2′-(p-phenyl­enedi­oxy)diacetato-κ(2) O:O′]
title catena-Poly[[aqua­bis­(pyridine-κN)copper(II)]-μ-2,2′-(p-phenyl­enedi­oxy)diacetato-κ(2) O:O′]
title_full catena-Poly[[aqua­bis­(pyridine-κN)copper(II)]-μ-2,2′-(p-phenyl­enedi­oxy)diacetato-κ(2) O:O′]
title_fullStr catena-Poly[[aqua­bis­(pyridine-κN)copper(II)]-μ-2,2′-(p-phenyl­enedi­oxy)diacetato-κ(2) O:O′]
title_full_unstemmed catena-Poly[[aqua­bis­(pyridine-κN)copper(II)]-μ-2,2′-(p-phenyl­enedi­oxy)diacetato-κ(2) O:O′]
title_short catena-Poly[[aqua­bis­(pyridine-κN)copper(II)]-μ-2,2′-(p-phenyl­enedi­oxy)diacetato-κ(2) O:O′]
title_sort catena-poly[[aqua­bis­(pyridine-κn)copper(ii)]-μ-2,2′-(p-phenyl­enedi­oxy)diacetato-κ(2) o:o′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983391/
https://www.ncbi.nlm.nih.gov/pubmed/21587426
http://dx.doi.org/10.1107/S1600536810036469
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