Cargando…
6-Amino-5-(1-amino-2,2-dicyanovinyl)-3,3a,4,5-tetrahydro-2H-indene-4-spiro-1′-cyclopentane-3a,7-dicarbonitrile–thiophene-2-carbaldehyde (1/0.5)
In each of the two independent indene-4-spiropentane molecules in the asymmetric unit of the title 2:1 adduct, C(19)H(18)N(6)·0.5C(5)H(4)OS, the cyclohexene ring adopts a half-chair conformation and the cyclopentene and cyclopentane rings adopt envelope conformations. The mean plane through the...
Autores principales: | , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983394/ https://www.ncbi.nlm.nih.gov/pubmed/21587485 http://dx.doi.org/10.1107/S1600536810034434 |
Sumario: | In each of the two independent indene-4-spiropentane molecules in the asymmetric unit of the title 2:1 adduct, C(19)H(18)N(6)·0.5C(5)H(4)OS, the cyclohexene ring adopts a half-chair conformation and the cyclopentene and cyclopentane rings adopt envelope conformations. The mean plane through the cyclohexene/cyclopentene fused system is aligned at a dihedral angle of 77.9 (1)° with respect to the mean plane through the cyclopentane ring in one molecule and 87.0 (1)° in the other. In the crystal, adjacent indene-4-spiropentane molecules are linked by N—H⋯N hydrogen bonds into a three-dimensional network. The spaces within the network are occupied by the thiophene-2-carbaldehyde molecules. The thiophene-2-carbaldehyde unit is disordered over two positions of equal occupancy. The crystal studied was found to be a non-morohedral twin with two minor twin components of 18.4 and 9.7%. |
---|