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6-Amino-5-(1-amino-2,2-dicyano­vin­yl)-3,3a,4,5-tetra­hydro-2H-indene-4-spiro-1′-cyclo­pentane-3a,7-dicarbonitrile–thio­phene-2-carbaldehyde (1/0.5)

In each of the two independent indene-4-spiro­pentane mol­ecules in the asymmetric unit of the title 2:1 adduct, C(19)H(18)N(6)·0.5C(5)H(4)OS, the cyclo­hexene ring adopts a half-chair conformation and the cyclo­pentene and cyclo­pentane rings adopt envelope conformations. The mean plane through the...

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Detalles Bibliográficos
Autores principales: Asiri, Abdullah M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983394/
https://www.ncbi.nlm.nih.gov/pubmed/21587485
http://dx.doi.org/10.1107/S1600536810034434
Descripción
Sumario:In each of the two independent indene-4-spiro­pentane mol­ecules in the asymmetric unit of the title 2:1 adduct, C(19)H(18)N(6)·0.5C(5)H(4)OS, the cyclo­hexene ring adopts a half-chair conformation and the cyclo­pentene and cyclo­pentane rings adopt envelope conformations. The mean plane through the cyclo­hexene/cyclo­pentene fused system is aligned at a dihedral angle of 77.9 (1)° with respect to the mean plane through the cyclo­pentane ring in one mol­ecule and 87.0 (1)° in the other. In the crystal, adjacent indene-4-spiro­pentane mol­ecules are linked by N—H⋯N hydrogen bonds into a three-dimensional network. The spaces within the network are occupied by the thio­phene-2-carbaldehyde mol­ecules. The thio­phene-2-carbaldehyde unit is disordered over two positions of equal occupancy. The crystal studied was found to be a non-morohedral twin with two minor twin components of 18.4 and 9.7%.