2-(2-Nitro­anilino)-4,5,6,7-tetra­hydro­benzo[b]thio­phene-3-carbonitrile

The title compound, C(15)H(13)N(3)O(2)S, was synthesized by the reaction of 2-amino-5,6,7,8-tetra­hydro-4H-cyclo­hepta­[b]thio­phene-3-carbonitrile and o-fluoro­nitro­benzene. The dihedral angle between the thio­phene and nitro­phenyl rings is 75.15 (2)°. In the crystal, inter­molecular N—H⋯N and C—...

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Detalles Bibliográficos
Autores principales: Mendonça Junior, Francisco J.B., de Lima, Maria do Carmo A., Galdino, Suely L., Pitta, Ivan R., de Simone, Carlos A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983395/
https://www.ncbi.nlm.nih.gov/pubmed/21587533
http://dx.doi.org/10.1107/S1600536810035439
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author Mendonça Junior, Francisco J.B.
de Lima, Maria do Carmo A.
Galdino, Suely L.
Pitta, Ivan R.
de Simone, Carlos A.
author_facet Mendonça Junior, Francisco J.B.
de Lima, Maria do Carmo A.
Galdino, Suely L.
Pitta, Ivan R.
de Simone, Carlos A.
author_sort Mendonça Junior, Francisco J.B.
collection PubMed
description The title compound, C(15)H(13)N(3)O(2)S, was synthesized by the reaction of 2-amino-5,6,7,8-tetra­hydro-4H-cyclo­hepta­[b]thio­phene-3-carbonitrile and o-fluoro­nitro­benzene. The dihedral angle between the thio­phene and nitro­phenyl rings is 75.15 (2)°. In the crystal, inter­molecular N—H⋯N and C—H⋯O inter­actions lead to the formation of a supra­molecular chain extending along the c-axis direction.
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spelling pubmed-29833952010-12-30 2-(2-Nitro­anilino)-4,5,6,7-tetra­hydro­benzo[b]thio­phene-3-carbonitrile Mendonça Junior, Francisco J.B. de Lima, Maria do Carmo A. Galdino, Suely L. Pitta, Ivan R. de Simone, Carlos A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(13)N(3)O(2)S, was synthesized by the reaction of 2-amino-5,6,7,8-tetra­hydro-4H-cyclo­hepta­[b]thio­phene-3-carbonitrile and o-fluoro­nitro­benzene. The dihedral angle between the thio­phene and nitro­phenyl rings is 75.15 (2)°. In the crystal, inter­molecular N—H⋯N and C—H⋯O inter­actions lead to the formation of a supra­molecular chain extending along the c-axis direction. International Union of Crystallography 2010-09-11 /pmc/articles/PMC2983395/ /pubmed/21587533 http://dx.doi.org/10.1107/S1600536810035439 Text en © Mendonça Junior et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mendonça Junior, Francisco J.B.
de Lima, Maria do Carmo A.
Galdino, Suely L.
Pitta, Ivan R.
de Simone, Carlos A.
2-(2-Nitro­anilino)-4,5,6,7-tetra­hydro­benzo[b]thio­phene-3-carbonitrile
title 2-(2-Nitro­anilino)-4,5,6,7-tetra­hydro­benzo[b]thio­phene-3-carbonitrile
title_full 2-(2-Nitro­anilino)-4,5,6,7-tetra­hydro­benzo[b]thio­phene-3-carbonitrile
title_fullStr 2-(2-Nitro­anilino)-4,5,6,7-tetra­hydro­benzo[b]thio­phene-3-carbonitrile
title_full_unstemmed 2-(2-Nitro­anilino)-4,5,6,7-tetra­hydro­benzo[b]thio­phene-3-carbonitrile
title_short 2-(2-Nitro­anilino)-4,5,6,7-tetra­hydro­benzo[b]thio­phene-3-carbonitrile
title_sort 2-(2-nitro­anilino)-4,5,6,7-tetra­hydro­benzo[b]thio­phene-3-carbonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983395/
https://www.ncbi.nlm.nih.gov/pubmed/21587533
http://dx.doi.org/10.1107/S1600536810035439
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