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(η(5)-Pentamethylcyclopentadienyl)(η(6)-toluene)ruthenium(II) hexafluoridophosphate
In the title complex, [Ru(C(7)H(8))(C(10)H(15))]PF(6), the cation lies on a mirror plane and the anion lies on an inversion center. The distance between the Ru atom and the centroid of the benzene ring is 1.706 (5) Å and the distance between the Ru atom and the cyclopentadienyl ring is 1.811 (5) Å...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983397/ https://www.ncbi.nlm.nih.gov/pubmed/21587411 http://dx.doi.org/10.1107/S1600536810036299 |
| _version_ | 1782191872762970112 |
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| author | O, Wylie W. N. Lough, Alan J. Morris, Robert H. |
| author_facet | O, Wylie W. N. Lough, Alan J. Morris, Robert H. |
| author_sort | O, Wylie W. N. |
| collection | PubMed |
| description | In the title complex, [Ru(C(7)H(8))(C(10)H(15))]PF(6), the cation lies on a mirror plane and the anion lies on an inversion center. The distance between the Ru atom and the centroid of the benzene ring is 1.706 (5) Å and the distance between the Ru atom and the cyclopentadienyl ring is 1.811 (5) Å. The crystal structure is stabilized by weak C—H⋯F hydrogen bonds. The H atoms of the methyl groups which lie on the mirror plane are disordered over two sites with equal occupancies. |
| format | Text |
| id | pubmed-2983397 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29833972010-12-30 (η(5)-Pentamethylcyclopentadienyl)(η(6)-toluene)ruthenium(II) hexafluoridophosphate O, Wylie W. N. Lough, Alan J. Morris, Robert H. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ru(C(7)H(8))(C(10)H(15))]PF(6), the cation lies on a mirror plane and the anion lies on an inversion center. The distance between the Ru atom and the centroid of the benzene ring is 1.706 (5) Å and the distance between the Ru atom and the cyclopentadienyl ring is 1.811 (5) Å. The crystal structure is stabilized by weak C—H⋯F hydrogen bonds. The H atoms of the methyl groups which lie on the mirror plane are disordered over two sites with equal occupancies. International Union of Crystallography 2010-09-15 /pmc/articles/PMC2983397/ /pubmed/21587411 http://dx.doi.org/10.1107/S1600536810036299 Text en © O et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers O, Wylie W. N. Lough, Alan J. Morris, Robert H. (η(5)-Pentamethylcyclopentadienyl)(η(6)-toluene)ruthenium(II) hexafluoridophosphate |
| title | (η(5)-Pentamethylcyclopentadienyl)(η(6)-toluene)ruthenium(II) hexafluoridophosphate |
| title_full | (η(5)-Pentamethylcyclopentadienyl)(η(6)-toluene)ruthenium(II) hexafluoridophosphate |
| title_fullStr | (η(5)-Pentamethylcyclopentadienyl)(η(6)-toluene)ruthenium(II) hexafluoridophosphate |
| title_full_unstemmed | (η(5)-Pentamethylcyclopentadienyl)(η(6)-toluene)ruthenium(II) hexafluoridophosphate |
| title_short | (η(5)-Pentamethylcyclopentadienyl)(η(6)-toluene)ruthenium(II) hexafluoridophosphate |
| title_sort | (η(5)-pentamethylcyclopentadienyl)(η(6)-toluene)ruthenium(ii) hexafluoridophosphate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983397/ https://www.ncbi.nlm.nih.gov/pubmed/21587411 http://dx.doi.org/10.1107/S1600536810036299 |
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