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4-Cyano-1-(4-nitrobenzyl)pyridinium bis(2-thioxo-1,3-dithiole-4,5-dithiolato-κ(2) S (4),S (5))nickelate(III)
In the title salt, (C(13)H(10)N(3)O(2))[Ni(C(3)S(5))(2)], the Ni(III) cation is S,S′-chelated by two 2-thioxo-1,3-dithiole-4,5-dithiolate anions in a distorted square-planar geometry. The complex anion is approximately planar with a maximum deviation of 0.097 (1) Å. In the 1-(4-nitrobenzyl)-4-cya...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983398/ https://www.ncbi.nlm.nih.gov/pubmed/21587448 http://dx.doi.org/10.1107/S1600536810037426 |
Sumario: | In the title salt, (C(13)H(10)N(3)O(2))[Ni(C(3)S(5))(2)], the Ni(III) cation is S,S′-chelated by two 2-thioxo-1,3-dithiole-4,5-dithiolate anions in a distorted square-planar geometry. The complex anion is approximately planar with a maximum deviation of 0.097 (1) Å. In the 1-(4-nitrobenzyl)-4-cyanopyridinium cation, the pyridine ring is twisted at a dihedral angle of 73.84 (16)° with respect to the benzene ring. π-π stacking is observed between nearly parallel [dihedral angle = 4.71 (7)°] dithiole and benzene rings, the centroid–centroid distance being 3.791 (2) Å. |
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