4-Cyano-1-(4-nitro­benz­yl)pyridinium bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato-κ(2) S (4),S (5))nickelate(III)

In the title salt, (C(13)H(10)N(3)O(2))[Ni(C(3)S(5))(2)], the Ni(III) cation is S,S′-chelated by two 2-thioxo-1,3-dithiole-4,5-dithiol­ate anions in a distorted square-planar geometry. The complex anion is approximately planar with a maximum deviation of 0.097 (1) Å. In the 1-(4-nitro­benz­yl)-4-cya...

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Detalles Bibliográficos
Autores principales: Li, Kai-Hui, Lei, Qing-Duo, Mei, Chong-Zhen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983398/
https://www.ncbi.nlm.nih.gov/pubmed/21587448
http://dx.doi.org/10.1107/S1600536810037426
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author Li, Kai-Hui
Lei, Qing-Duo
Mei, Chong-Zhen
author_facet Li, Kai-Hui
Lei, Qing-Duo
Mei, Chong-Zhen
author_sort Li, Kai-Hui
collection PubMed
description In the title salt, (C(13)H(10)N(3)O(2))[Ni(C(3)S(5))(2)], the Ni(III) cation is S,S′-chelated by two 2-thioxo-1,3-dithiole-4,5-dithiol­ate anions in a distorted square-planar geometry. The complex anion is approximately planar with a maximum deviation of 0.097 (1) Å. In the 1-(4-nitro­benz­yl)-4-cyano­pyridinium cation, the pyridine ring is twisted at a dihedral angle of 73.84 (16)° with respect to the benzene ring. π-π stacking is observed between nearly parallel [dihedral angle = 4.71 (7)°] dithiole and benzene rings, the centroid–centroid distance being 3.791 (2) Å.
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spelling pubmed-29833982010-12-30 4-Cyano-1-(4-nitro­benz­yl)pyridinium bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato-κ(2) S (4),S (5))nickelate(III) Li, Kai-Hui Lei, Qing-Duo Mei, Chong-Zhen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, (C(13)H(10)N(3)O(2))[Ni(C(3)S(5))(2)], the Ni(III) cation is S,S′-chelated by two 2-thioxo-1,3-dithiole-4,5-dithiol­ate anions in a distorted square-planar geometry. The complex anion is approximately planar with a maximum deviation of 0.097 (1) Å. In the 1-(4-nitro­benz­yl)-4-cyano­pyridinium cation, the pyridine ring is twisted at a dihedral angle of 73.84 (16)° with respect to the benzene ring. π-π stacking is observed between nearly parallel [dihedral angle = 4.71 (7)°] dithiole and benzene rings, the centroid–centroid distance being 3.791 (2) Å. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983398/ /pubmed/21587448 http://dx.doi.org/10.1107/S1600536810037426 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Kai-Hui
Lei, Qing-Duo
Mei, Chong-Zhen
4-Cyano-1-(4-nitro­benz­yl)pyridinium bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato-κ(2) S (4),S (5))nickelate(III)
title 4-Cyano-1-(4-nitro­benz­yl)pyridinium bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato-κ(2) S (4),S (5))nickelate(III)
title_full 4-Cyano-1-(4-nitro­benz­yl)pyridinium bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato-κ(2) S (4),S (5))nickelate(III)
title_fullStr 4-Cyano-1-(4-nitro­benz­yl)pyridinium bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato-κ(2) S (4),S (5))nickelate(III)
title_full_unstemmed 4-Cyano-1-(4-nitro­benz­yl)pyridinium bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato-κ(2) S (4),S (5))nickelate(III)
title_short 4-Cyano-1-(4-nitro­benz­yl)pyridinium bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato-κ(2) S (4),S (5))nickelate(III)
title_sort 4-cyano-1-(4-nitro­benz­yl)pyridinium bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato-κ(2) s (4),s (5))nickelate(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983398/
https://www.ncbi.nlm.nih.gov/pubmed/21587448
http://dx.doi.org/10.1107/S1600536810037426
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AT meichongzhen 4cyano14nitrobenzylpyridiniumbis2thioxo13dithiole45dithiolatok2s4s5nickelateiii

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