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Bis[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]dithio­cyanato-κN,κS-cadmium(II)

The mol­ecular structure of the mononuclear complex, [Cd(SCN)(2)(C(8)H(7)N(3))(2)], contains a Cd(II) atom in a distorted octa­hedral coordination defined by five N atoms from two bidentate chelate 2-(1H-pyrazol-3-yl)pyridine ligands and by one SCN(−) anion. The second SCN(−) anion provides its S at...

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Detalles Bibliográficos
Autores principales: Cai, Hua, Guo, Ying, Li, Jian-Gang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983401/
https://www.ncbi.nlm.nih.gov/pubmed/21587364
http://dx.doi.org/10.1107/S1600536810034604
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author Cai, Hua
Guo, Ying
Li, Jian-Gang
author_facet Cai, Hua
Guo, Ying
Li, Jian-Gang
author_sort Cai, Hua
collection PubMed
description The mol­ecular structure of the mononuclear complex, [Cd(SCN)(2)(C(8)H(7)N(3))(2)], contains a Cd(II) atom in a distorted octa­hedral coordination defined by five N atoms from two bidentate chelate 2-(1H-pyrazol-3-yl)pyridine ligands and by one SCN(−) anion. The second SCN(−) anion provides its S atom for completion of the coordination sphere. The complex is linked to four others by N—H⋯N and N—H⋯S hydrogen-bonding inter­actions between the pyrazol N—H group and the terminal S and N atoms of neighbouring SCN(−) anions. This arrangement leads to the formation of sheets parallel to (100). Face-to-face π–π stacking inter­actions with shortest inter­planar distances of 3.805 (2) and 3.696 (2) Å help to consolidate the crystal packing.
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spelling pubmed-29834012010-12-30 Bis[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]dithio­cyanato-κN,κS-cadmium(II) Cai, Hua Guo, Ying Li, Jian-Gang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mol­ecular structure of the mononuclear complex, [Cd(SCN)(2)(C(8)H(7)N(3))(2)], contains a Cd(II) atom in a distorted octa­hedral coordination defined by five N atoms from two bidentate chelate 2-(1H-pyrazol-3-yl)pyridine ligands and by one SCN(−) anion. The second SCN(−) anion provides its S atom for completion of the coordination sphere. The complex is linked to four others by N—H⋯N and N—H⋯S hydrogen-bonding inter­actions between the pyrazol N—H group and the terminal S and N atoms of neighbouring SCN(−) anions. This arrangement leads to the formation of sheets parallel to (100). Face-to-face π–π stacking inter­actions with shortest inter­planar distances of 3.805 (2) and 3.696 (2) Å help to consolidate the crystal packing. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983401/ /pubmed/21587364 http://dx.doi.org/10.1107/S1600536810034604 Text en © Cai et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cai, Hua
Guo, Ying
Li, Jian-Gang
Bis[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]dithio­cyanato-κN,κS-cadmium(II)
title Bis[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]dithio­cyanato-κN,κS-cadmium(II)
title_full Bis[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]dithio­cyanato-κN,κS-cadmium(II)
title_fullStr Bis[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]dithio­cyanato-κN,κS-cadmium(II)
title_full_unstemmed Bis[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]dithio­cyanato-κN,κS-cadmium(II)
title_short Bis[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]dithio­cyanato-κN,κS-cadmium(II)
title_sort bis[2-(1h-pyrazol-3-yl-κn (2))pyridine-κn]dithio­cyanato-κn,κs-cadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983401/
https://www.ncbi.nlm.nih.gov/pubmed/21587364
http://dx.doi.org/10.1107/S1600536810034604
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