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Bis[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]dithiocyanato-κN,κS-cadmium(II)
The molecular structure of the mononuclear complex, [Cd(SCN)(2)(C(8)H(7)N(3))(2)], contains a Cd(II) atom in a distorted octahedral coordination defined by five N atoms from two bidentate chelate 2-(1H-pyrazol-3-yl)pyridine ligands and by one SCN(−) anion. The second SCN(−) anion provides its S at...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983401/ https://www.ncbi.nlm.nih.gov/pubmed/21587364 http://dx.doi.org/10.1107/S1600536810034604 |
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author | Cai, Hua Guo, Ying Li, Jian-Gang |
author_facet | Cai, Hua Guo, Ying Li, Jian-Gang |
author_sort | Cai, Hua |
collection | PubMed |
description | The molecular structure of the mononuclear complex, [Cd(SCN)(2)(C(8)H(7)N(3))(2)], contains a Cd(II) atom in a distorted octahedral coordination defined by five N atoms from two bidentate chelate 2-(1H-pyrazol-3-yl)pyridine ligands and by one SCN(−) anion. The second SCN(−) anion provides its S atom for completion of the coordination sphere. The complex is linked to four others by N—H⋯N and N—H⋯S hydrogen-bonding interactions between the pyrazol N—H group and the terminal S and N atoms of neighbouring SCN(−) anions. This arrangement leads to the formation of sheets parallel to (100). Face-to-face π–π stacking interactions with shortest interplanar distances of 3.805 (2) and 3.696 (2) Å help to consolidate the crystal packing. |
format | Text |
id | pubmed-2983401 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29834012010-12-30 Bis[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]dithiocyanato-κN,κS-cadmium(II) Cai, Hua Guo, Ying Li, Jian-Gang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The molecular structure of the mononuclear complex, [Cd(SCN)(2)(C(8)H(7)N(3))(2)], contains a Cd(II) atom in a distorted octahedral coordination defined by five N atoms from two bidentate chelate 2-(1H-pyrazol-3-yl)pyridine ligands and by one SCN(−) anion. The second SCN(−) anion provides its S atom for completion of the coordination sphere. The complex is linked to four others by N—H⋯N and N—H⋯S hydrogen-bonding interactions between the pyrazol N—H group and the terminal S and N atoms of neighbouring SCN(−) anions. This arrangement leads to the formation of sheets parallel to (100). Face-to-face π–π stacking interactions with shortest interplanar distances of 3.805 (2) and 3.696 (2) Å help to consolidate the crystal packing. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983401/ /pubmed/21587364 http://dx.doi.org/10.1107/S1600536810034604 Text en © Cai et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Cai, Hua Guo, Ying Li, Jian-Gang Bis[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]dithiocyanato-κN,κS-cadmium(II) |
title | Bis[2-(1H-pyrazol-3-yl-κN
(2))pyridine-κN]dithiocyanato-κN,κS-cadmium(II) |
title_full | Bis[2-(1H-pyrazol-3-yl-κN
(2))pyridine-κN]dithiocyanato-κN,κS-cadmium(II) |
title_fullStr | Bis[2-(1H-pyrazol-3-yl-κN
(2))pyridine-κN]dithiocyanato-κN,κS-cadmium(II) |
title_full_unstemmed | Bis[2-(1H-pyrazol-3-yl-κN
(2))pyridine-κN]dithiocyanato-κN,κS-cadmium(II) |
title_short | Bis[2-(1H-pyrazol-3-yl-κN
(2))pyridine-κN]dithiocyanato-κN,κS-cadmium(II) |
title_sort | bis[2-(1h-pyrazol-3-yl-κn
(2))pyridine-κn]dithiocyanato-κn,κs-cadmium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983401/ https://www.ncbi.nlm.nih.gov/pubmed/21587364 http://dx.doi.org/10.1107/S1600536810034604 |
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