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Aqua­(benzene-1,2-dicarboxyl­ato-κO)bis­[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]cadmium(II)

In the mononuclear title complex, [Cd(C(8)H(4)O(4))(C(8)H(7)N(3))(2)(H(2)O)], the Cd(II) atom is six-coordinated in a distorted octa­hedral geometry by four N atoms from two bidentate chelating 2-(1H-pyrazol-3-yl)pyridine ligands, one O atom from a benzene-1,2-dicarboxyl­ate ligand and one water mol...

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Detalles Bibliográficos
Autor principal: Guo, Jian-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983402/
https://www.ncbi.nlm.nih.gov/pubmed/21587365
http://dx.doi.org/10.1107/S1600536810034616
Descripción
Sumario:In the mononuclear title complex, [Cd(C(8)H(4)O(4))(C(8)H(7)N(3))(2)(H(2)O)], the Cd(II) atom is six-coordinated in a distorted octa­hedral geometry by four N atoms from two bidentate chelating 2-(1H-pyrazol-3-yl)pyridine ligands, one O atom from a benzene-1,2-dicarboxyl­ate ligand and one water mol­ecule. The mol­ecular structure features intra­molecular O—H⋯O and N—H⋯O hydrogen bonds. In the crystal structure, the complex mol­ecules are assembled into a two-dimensional supra­molecular layer parallel to (011) via O—H⋯O and N—H⋯O hydrogen bonds and π–π stacking inter­actions between the pyridyl and pyrazole rings [centroid–centroid distances = 3.544 (2) and 3.722 (3) Å].