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Aqua(benzene-1,2-dicarboxylato-κO)bis[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]cadmium(II)
In the mononuclear title complex, [Cd(C(8)H(4)O(4))(C(8)H(7)N(3))(2)(H(2)O)], the Cd(II) atom is six-coordinated in a distorted octahedral geometry by four N atoms from two bidentate chelating 2-(1H-pyrazol-3-yl)pyridine ligands, one O atom from a benzene-1,2-dicarboxylate ligand and one water mol...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983402/ https://www.ncbi.nlm.nih.gov/pubmed/21587365 http://dx.doi.org/10.1107/S1600536810034616 |
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author | Guo, Jian-Hua |
author_facet | Guo, Jian-Hua |
author_sort | Guo, Jian-Hua |
collection | PubMed |
description | In the mononuclear title complex, [Cd(C(8)H(4)O(4))(C(8)H(7)N(3))(2)(H(2)O)], the Cd(II) atom is six-coordinated in a distorted octahedral geometry by four N atoms from two bidentate chelating 2-(1H-pyrazol-3-yl)pyridine ligands, one O atom from a benzene-1,2-dicarboxylate ligand and one water molecule. The molecular structure features intramolecular O—H⋯O and N—H⋯O hydrogen bonds. In the crystal structure, the complex molecules are assembled into a two-dimensional supramolecular layer parallel to (011) via O—H⋯O and N—H⋯O hydrogen bonds and π–π stacking interactions between the pyridyl and pyrazole rings [centroid–centroid distances = 3.544 (2) and 3.722 (3) Å]. |
format | Text |
id | pubmed-2983402 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29834022010-12-30 Aqua(benzene-1,2-dicarboxylato-κO)bis[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]cadmium(II) Guo, Jian-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [Cd(C(8)H(4)O(4))(C(8)H(7)N(3))(2)(H(2)O)], the Cd(II) atom is six-coordinated in a distorted octahedral geometry by four N atoms from two bidentate chelating 2-(1H-pyrazol-3-yl)pyridine ligands, one O atom from a benzene-1,2-dicarboxylate ligand and one water molecule. The molecular structure features intramolecular O—H⋯O and N—H⋯O hydrogen bonds. In the crystal structure, the complex molecules are assembled into a two-dimensional supramolecular layer parallel to (011) via O—H⋯O and N—H⋯O hydrogen bonds and π–π stacking interactions between the pyridyl and pyrazole rings [centroid–centroid distances = 3.544 (2) and 3.722 (3) Å]. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983402/ /pubmed/21587365 http://dx.doi.org/10.1107/S1600536810034616 Text en © Jian-Hua Guo 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Guo, Jian-Hua Aqua(benzene-1,2-dicarboxylato-κO)bis[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]cadmium(II) |
title | Aqua(benzene-1,2-dicarboxylato-κO)bis[2-(1H-pyrazol-3-yl-κN
(2))pyridine-κN]cadmium(II) |
title_full | Aqua(benzene-1,2-dicarboxylato-κO)bis[2-(1H-pyrazol-3-yl-κN
(2))pyridine-κN]cadmium(II) |
title_fullStr | Aqua(benzene-1,2-dicarboxylato-κO)bis[2-(1H-pyrazol-3-yl-κN
(2))pyridine-κN]cadmium(II) |
title_full_unstemmed | Aqua(benzene-1,2-dicarboxylato-κO)bis[2-(1H-pyrazol-3-yl-κN
(2))pyridine-κN]cadmium(II) |
title_short | Aqua(benzene-1,2-dicarboxylato-κO)bis[2-(1H-pyrazol-3-yl-κN
(2))pyridine-κN]cadmium(II) |
title_sort | aqua(benzene-1,2-dicarboxylato-κo)bis[2-(1h-pyrazol-3-yl-κn
(2))pyridine-κn]cadmium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983402/ https://www.ncbi.nlm.nih.gov/pubmed/21587365 http://dx.doi.org/10.1107/S1600536810034616 |
work_keys_str_mv | AT guojianhua aquabenzene12dicarboxylatokobis21hpyrazol3ylkn2pyridinekncadmiumii |