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Aqua­(benzene-1,2-dicarboxyl­ato-κO)bis­[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]cadmium(II)

In the mononuclear title complex, [Cd(C(8)H(4)O(4))(C(8)H(7)N(3))(2)(H(2)O)], the Cd(II) atom is six-coordinated in a distorted octa­hedral geometry by four N atoms from two bidentate chelating 2-(1H-pyrazol-3-yl)pyridine ligands, one O atom from a benzene-1,2-dicarboxyl­ate ligand and one water mol...

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Detalles Bibliográficos
Autor principal: Guo, Jian-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983402/
https://www.ncbi.nlm.nih.gov/pubmed/21587365
http://dx.doi.org/10.1107/S1600536810034616
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author Guo, Jian-Hua
author_facet Guo, Jian-Hua
author_sort Guo, Jian-Hua
collection PubMed
description In the mononuclear title complex, [Cd(C(8)H(4)O(4))(C(8)H(7)N(3))(2)(H(2)O)], the Cd(II) atom is six-coordinated in a distorted octa­hedral geometry by four N atoms from two bidentate chelating 2-(1H-pyrazol-3-yl)pyridine ligands, one O atom from a benzene-1,2-dicarboxyl­ate ligand and one water mol­ecule. The mol­ecular structure features intra­molecular O—H⋯O and N—H⋯O hydrogen bonds. In the crystal structure, the complex mol­ecules are assembled into a two-dimensional supra­molecular layer parallel to (011) via O—H⋯O and N—H⋯O hydrogen bonds and π–π stacking inter­actions between the pyridyl and pyrazole rings [centroid–centroid distances = 3.544 (2) and 3.722 (3) Å].
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spelling pubmed-29834022010-12-30 Aqua­(benzene-1,2-dicarboxyl­ato-κO)bis­[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]cadmium(II) Guo, Jian-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [Cd(C(8)H(4)O(4))(C(8)H(7)N(3))(2)(H(2)O)], the Cd(II) atom is six-coordinated in a distorted octa­hedral geometry by four N atoms from two bidentate chelating 2-(1H-pyrazol-3-yl)pyridine ligands, one O atom from a benzene-1,2-dicarboxyl­ate ligand and one water mol­ecule. The mol­ecular structure features intra­molecular O—H⋯O and N—H⋯O hydrogen bonds. In the crystal structure, the complex mol­ecules are assembled into a two-dimensional supra­molecular layer parallel to (011) via O—H⋯O and N—H⋯O hydrogen bonds and π–π stacking inter­actions between the pyridyl and pyrazole rings [centroid–centroid distances = 3.544 (2) and 3.722 (3) Å]. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983402/ /pubmed/21587365 http://dx.doi.org/10.1107/S1600536810034616 Text en © Jian-Hua Guo 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Jian-Hua
Aqua­(benzene-1,2-dicarboxyl­ato-κO)bis­[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]cadmium(II)
title Aqua­(benzene-1,2-dicarboxyl­ato-κO)bis­[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]cadmium(II)
title_full Aqua­(benzene-1,2-dicarboxyl­ato-κO)bis­[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]cadmium(II)
title_fullStr Aqua­(benzene-1,2-dicarboxyl­ato-κO)bis­[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]cadmium(II)
title_full_unstemmed Aqua­(benzene-1,2-dicarboxyl­ato-κO)bis­[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]cadmium(II)
title_short Aqua­(benzene-1,2-dicarboxyl­ato-κO)bis­[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]cadmium(II)
title_sort aqua­(benzene-1,2-dicarboxyl­ato-κo)bis­[2-(1h-pyrazol-3-yl-κn (2))pyridine-κn]cadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983402/
https://www.ncbi.nlm.nih.gov/pubmed/21587365
http://dx.doi.org/10.1107/S1600536810034616
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