1-Phenyl­piperazine-1,4-diium bis­(hydrogen sulfate)

In the title compound, C(10)H(16)N(2) (2+)·2HSO(4) (−), the S atoms adopt slightly distorted tetra­hedral geometry and the diprotonated piperazine ring adopts a chair conformation. In the crystal, the 1-phenyl­piperazine-1,4-diium cations are anchored between chains formed by the sulfate entities vi...

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Detalles Bibliográficos
Autores principales: Marouani, Houda, Rzaigui, Mohamed, Al-Deyab, Salem S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983403/
https://www.ncbi.nlm.nih.gov/pubmed/21587588
http://dx.doi.org/10.1107/S1600536810037001
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author Marouani, Houda
Rzaigui, Mohamed
Al-Deyab, Salem S.
author_facet Marouani, Houda
Rzaigui, Mohamed
Al-Deyab, Salem S.
author_sort Marouani, Houda
collection PubMed
description In the title compound, C(10)H(16)N(2) (2+)·2HSO(4) (−), the S atoms adopt slightly distorted tetra­hedral geometry and the diprotonated piperazine ring adopts a chair conformation. In the crystal, the 1-phenyl­piperazine-1,4-diium cations are anchored between chains formed by the sulfate entities via inter­molecular bifurcated N—H⋯(O,O) and weak C—H⋯O hydrogen bonds. These hydrogen bonds contribute to the cohesion and stability of the network of the crystal structure.
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spelling pubmed-29834032010-12-30 1-Phenyl­piperazine-1,4-diium bis­(hydrogen sulfate) Marouani, Houda Rzaigui, Mohamed Al-Deyab, Salem S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(16)N(2) (2+)·2HSO(4) (−), the S atoms adopt slightly distorted tetra­hedral geometry and the diprotonated piperazine ring adopts a chair conformation. In the crystal, the 1-phenyl­piperazine-1,4-diium cations are anchored between chains formed by the sulfate entities via inter­molecular bifurcated N—H⋯(O,O) and weak C—H⋯O hydrogen bonds. These hydrogen bonds contribute to the cohesion and stability of the network of the crystal structure. International Union of Crystallography 2010-09-25 /pmc/articles/PMC2983403/ /pubmed/21587588 http://dx.doi.org/10.1107/S1600536810037001 Text en © Marouani et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Marouani, Houda
Rzaigui, Mohamed
Al-Deyab, Salem S.
1-Phenyl­piperazine-1,4-diium bis­(hydrogen sulfate)
title 1-Phenyl­piperazine-1,4-diium bis­(hydrogen sulfate)
title_full 1-Phenyl­piperazine-1,4-diium bis­(hydrogen sulfate)
title_fullStr 1-Phenyl­piperazine-1,4-diium bis­(hydrogen sulfate)
title_full_unstemmed 1-Phenyl­piperazine-1,4-diium bis­(hydrogen sulfate)
title_short 1-Phenyl­piperazine-1,4-diium bis­(hydrogen sulfate)
title_sort 1-phenyl­piperazine-1,4-diium bis­(hydrogen sulfate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983403/
https://www.ncbi.nlm.nih.gov/pubmed/21587588
http://dx.doi.org/10.1107/S1600536810037001
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AT rzaiguimohamed 1phenylpiperazine14diiumbishydrogensulfate
AT aldeyabsalems 1phenylpiperazine14diiumbishydrogensulfate

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