N,N′-Dibenzyl-N′′-(2,6-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide

The phosphoryl and carbonyl groups in the title compound, C(23)H(24)F(2)N(3)O(2)P, are anti to each other. The P atom is in a tetra­hedral coordination environment and the environment of each N atom is essentially planar, the average bond angles at the two N atoms being 119.9 and 119.1°. The H atom...

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Detalles Bibliográficos
Autores principales: Pourayoubi, Mehrdad, Tarahhomi, Atekeh, Rheingold, Arnold L., Golen, James A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983404/
https://www.ncbi.nlm.nih.gov/pubmed/21587518
http://dx.doi.org/10.1107/S1600536810035725
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author Pourayoubi, Mehrdad
Tarahhomi, Atekeh
Rheingold, Arnold L.
Golen, James A.
author_facet Pourayoubi, Mehrdad
Tarahhomi, Atekeh
Rheingold, Arnold L.
Golen, James A.
author_sort Pourayoubi, Mehrdad
collection PubMed
description The phosphoryl and carbonyl groups in the title compound, C(23)H(24)F(2)N(3)O(2)P, are anti to each other. The P atom is in a tetra­hedral coordination environment and the environment of each N atom is essentially planar, the average bond angles at the two N atoms being 119.9 and 119.1°. The H atom of the C(=O)NHP(=O) group is involved in an inter­molecular –P=O⋯H–N– hydrogen bond, forming centrosymmetric dimers.
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spelling pubmed-29834042010-12-30 N,N′-Dibenzyl-N′′-(2,6-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide Pourayoubi, Mehrdad Tarahhomi, Atekeh Rheingold, Arnold L. Golen, James A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The phosphoryl and carbonyl groups in the title compound, C(23)H(24)F(2)N(3)O(2)P, are anti to each other. The P atom is in a tetra­hedral coordination environment and the environment of each N atom is essentially planar, the average bond angles at the two N atoms being 119.9 and 119.1°. The H atom of the C(=O)NHP(=O) group is involved in an inter­molecular –P=O⋯H–N– hydrogen bond, forming centrosymmetric dimers. International Union of Crystallography 2010-09-11 /pmc/articles/PMC2983404/ /pubmed/21587518 http://dx.doi.org/10.1107/S1600536810035725 Text en © Pourayoubi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pourayoubi, Mehrdad
Tarahhomi, Atekeh
Rheingold, Arnold L.
Golen, James A.
N,N′-Dibenzyl-N′′-(2,6-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide
title N,N′-Dibenzyl-N′′-(2,6-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide
title_full N,N′-Dibenzyl-N′′-(2,6-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide
title_fullStr N,N′-Dibenzyl-N′′-(2,6-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide
title_full_unstemmed N,N′-Dibenzyl-N′′-(2,6-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide
title_short N,N′-Dibenzyl-N′′-(2,6-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide
title_sort n,n′-dibenzyl-n′′-(2,6-difluoro­benzo­yl)-n,n′-dimethyl­phospho­ric triamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983404/
https://www.ncbi.nlm.nih.gov/pubmed/21587518
http://dx.doi.org/10.1107/S1600536810035725
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