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Ethyl 4-(2,4-dichlorophenyl)-6-(6-methoxy-2-naphthyl)-2-oxocyclohex-3-ene-1-carboxylate
In the title compound, C(26)H(22)Cl(2)O(4), the cyclohexenone ring adopts an approximate half-chair conformation, with two C atoms displaced by −0.485 (6) and 0.218 (6) Å from the plane of the other four ring atoms. The dihedral angles between its four almost coplanar [maximum deviation = 0.006 (2)...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983411/ https://www.ncbi.nlm.nih.gov/pubmed/21587479 http://dx.doi.org/10.1107/S1600536810035130 |
Sumario: | In the title compound, C(26)H(22)Cl(2)O(4), the cyclohexenone ring adopts an approximate half-chair conformation, with two C atoms displaced by −0.485 (6) and 0.218 (6) Å from the plane of the other four ring atoms. The dihedral angles between its four almost coplanar [maximum deviation = 0.006 (2) Å] atoms and the benzene and naphthalene ring systems are 59.26 (13) and 79.94 (9)°, respectively. The dihedral angle between the aromatic rings systems is 77.14 (7)°. A short intramolecular C—H⋯Cl contact generates an S(6) ring. In the crystal, molecules are linked by C—H⋯O and C—H⋯Cl interactions to generate a three-dimensional network. |
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