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Ethyl 4-(2,4-dichlorophenyl)-6-(6-methoxy-2-naphthyl)-2-oxocyclohex-3-ene-1-carboxylate
In the title compound, C(26)H(22)Cl(2)O(4), the cyclohexenone ring adopts an approximate half-chair conformation, with two C atoms displaced by −0.485 (6) and 0.218 (6) Å from the plane of the other four ring atoms. The dihedral angles between its four almost coplanar [maximum deviation = 0.006 (2)...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983411/ https://www.ncbi.nlm.nih.gov/pubmed/21587479 http://dx.doi.org/10.1107/S1600536810035130 |
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author | Harrison, William T. A. Mayekar, A. N. Yathirajan, H. S. Narayana, B. Sarojini, B. K. |
author_facet | Harrison, William T. A. Mayekar, A. N. Yathirajan, H. S. Narayana, B. Sarojini, B. K. |
author_sort | Harrison, William T. A. |
collection | PubMed |
description | In the title compound, C(26)H(22)Cl(2)O(4), the cyclohexenone ring adopts an approximate half-chair conformation, with two C atoms displaced by −0.485 (6) and 0.218 (6) Å from the plane of the other four ring atoms. The dihedral angles between its four almost coplanar [maximum deviation = 0.006 (2) Å] atoms and the benzene and naphthalene ring systems are 59.26 (13) and 79.94 (9)°, respectively. The dihedral angle between the aromatic rings systems is 77.14 (7)°. A short intramolecular C—H⋯Cl contact generates an S(6) ring. In the crystal, molecules are linked by C—H⋯O and C—H⋯Cl interactions to generate a three-dimensional network. |
format | Text |
id | pubmed-2983411 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29834112010-12-30 Ethyl 4-(2,4-dichlorophenyl)-6-(6-methoxy-2-naphthyl)-2-oxocyclohex-3-ene-1-carboxylate Harrison, William T. A. Mayekar, A. N. Yathirajan, H. S. Narayana, B. Sarojini, B. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(22)Cl(2)O(4), the cyclohexenone ring adopts an approximate half-chair conformation, with two C atoms displaced by −0.485 (6) and 0.218 (6) Å from the plane of the other four ring atoms. The dihedral angles between its four almost coplanar [maximum deviation = 0.006 (2) Å] atoms and the benzene and naphthalene ring systems are 59.26 (13) and 79.94 (9)°, respectively. The dihedral angle between the aromatic rings systems is 77.14 (7)°. A short intramolecular C—H⋯Cl contact generates an S(6) ring. In the crystal, molecules are linked by C—H⋯O and C—H⋯Cl interactions to generate a three-dimensional network. International Union of Crystallography 2010-09-04 /pmc/articles/PMC2983411/ /pubmed/21587479 http://dx.doi.org/10.1107/S1600536810035130 Text en © Harrison et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Harrison, William T. A. Mayekar, A. N. Yathirajan, H. S. Narayana, B. Sarojini, B. K. Ethyl 4-(2,4-dichlorophenyl)-6-(6-methoxy-2-naphthyl)-2-oxocyclohex-3-ene-1-carboxylate |
title | Ethyl 4-(2,4-dichlorophenyl)-6-(6-methoxy-2-naphthyl)-2-oxocyclohex-3-ene-1-carboxylate |
title_full | Ethyl 4-(2,4-dichlorophenyl)-6-(6-methoxy-2-naphthyl)-2-oxocyclohex-3-ene-1-carboxylate |
title_fullStr | Ethyl 4-(2,4-dichlorophenyl)-6-(6-methoxy-2-naphthyl)-2-oxocyclohex-3-ene-1-carboxylate |
title_full_unstemmed | Ethyl 4-(2,4-dichlorophenyl)-6-(6-methoxy-2-naphthyl)-2-oxocyclohex-3-ene-1-carboxylate |
title_short | Ethyl 4-(2,4-dichlorophenyl)-6-(6-methoxy-2-naphthyl)-2-oxocyclohex-3-ene-1-carboxylate |
title_sort | ethyl 4-(2,4-dichlorophenyl)-6-(6-methoxy-2-naphthyl)-2-oxocyclohex-3-ene-1-carboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983411/ https://www.ncbi.nlm.nih.gov/pubmed/21587479 http://dx.doi.org/10.1107/S1600536810035130 |
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